Fluoride in the Nuclear Industry
Reports from the National Technical Information Service (NTIS)
1989 - 1995
 
 

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Due to the number of reports, the following
are the categories we present them.
(Note: these reports were cited on Toxline at Toxnet in April 2005)
Fluoride (all reports except Canada)
Fluoride: CANADA
Fluoride in the
Nuclear Industry
Note: many of the
Canadian communities
cited in these reports
border the US.
-
-
Note: this is a selected
list of reports.

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Order Number

Source Number

Date Published / Title / Author & Affiliation / Sponsor Agency Abstract /Keywords

NTIS/DE95007708

16p

1995. Application of the HGSYSTEM(sub 6) model to simulate atmospheric dispersion of UF(sub 6) releases from uranium enrichment plants./ECONOMICS

Authors:
Goode WD
Bloom SG
Keith KD

Oak Ridge K-25 Site, TN.

Supporting Agency: Department of Energy, Washington, DC.

Uranium hexafluoride is a dense, reactive gas used in Gaseous Diffusion Plants (GDPs) to make uranium enriched in the U-235 isotope. Large quantities of UF6 exist at the GDPs in the form of in-process gas and as a solid in storage cylinders; smaller amounts exist as hot liquid during transfer operations. If liquid UF6 is released to the environment, it immediately flashes to a solid and a dense gas that reacts rapidly with water vapor in the air to form solid particles of uranyl fluoride and hydrogen fluoride gas. Preliminary analyses were done on various accidental release scenarios to determine which scenarios must be considered in the safety analyses for the GDPS. These scenarios included gas releases due to failure of process equipment and liquid/gas releases resulting from a breach of transfer piping from a cylinder. A major goal of the calculations was to estimate the response time for mitigating actions in order to limit potential off-site consequences of these postulated releases. The HG [abstract truncated]

NTIS/DE96620534

U.S. Sales Only.

44p

1995. Toxicity levels to humans during acute exposure to hydrogen fluoride - An update.

Author: Halton DM

Atomic Energy Control Board, Ottawa (Ontario).

In March 1993, the Atomic Energy Control Board (AECB) commissioned and update of a 1984 review on the acute toxicity of hydrogen fluoride (HF). The study places particular emphasis on the effects of inhalation of gaseous HF and is divided into two main parts: a literature review and a lethal concentration (LC) estimation. The literature review summarizes data under four categories: animal studies, controlled human studies, community exposure, and industrial exposure. Data in these areas were critically reviewed for their relevance to lethal concentrations at LC(sub LO), LC(sub 10) and LC(sub 50) levels that were derived in the 1984 report. In the last ten years, only one relevant animal study has been published. No new controlled human studies were found but a community exposure incident was reported. There were three new industrial/accidental exposures reported since 1984. Evaluation of new data does not change the lethal concentration estimates made in the 1984 report, but does indicate the ab [abstract truncated]

NTIS/DE94018532

378p

1994. Remedial Action Plan and Site Design for Stabilization of the Inactive Uranium Mill Tailings Site, Maybell, Colorado. Appendixes to Attachment 3: Appendix A, Hydrological services calculations: Appendix B, Ground water quality by location, Final report.

Jacobs Engineering Group, Inc., Albuquerque, NM.

This report contains chemical analysis data for ground water for the following: elements; cyanides; chlorides; dissolved organic carbon; fluorides; silica; sulfates; sulfides; dissolved solids; nitrates; and nitrites. (ERA citation 19:029430) Progress rept. Sponsored by Department of Energy, Washington, DC.

NTIS/DE94007972

19p

1994. Recent results on the solubility of uranium and plutonium in Savannah River Site waste supernate.

Authors:
Karraker DG
Hobbs DT

Westinghouse Savannah River Co., Aiken, SC.

Sponsored by Department of Energy, Washington, DC.

High-level waste (HLW) is stored at the Savannah River Site (SRS) in a highly alkaline condition to prevent corrosion of the carbon steel storage tanks. Major components in the liquid phase include nitrate, hydroxide, nitrite, aluminate, carbonate and sulfate. Minor components include chloride, fluoride, oxalate and phosphate. The low solubility of uranium and plutonium in the HLW becomes significant to nuclear safety analyses when the supernate is evaporated to solids to conserve waste storage space and then redissolved to process for permanent disposal. The study of uranium and plutonium solubility in synthetic waste tank solutions was initiated to define actinide behavior during waste removal operations. Waste management '94, Tucson, AZ (United States), 27 Feb - 3 Mar 1994.

NTIS/PB95-154803

243p

1994. Public Health Assessment for Kerr-McGee Radiation Areas, West Chicago, Dupage County, Illinois, Region 5.

Kress Creek: CERCLIS No. ILD980823991;

Reed-Keppler Park: CERCLIS No. ILD980824007;

Residental Areas: CERCLIS No. ILD980824015;

Sewage Treatment Plant: CERCLIS No. ILD980824031.

Illinois State Dept. of Public Health, Springfield.

Sponsored by Agency for Toxic Substances and Disease Registry, Atlanta, GA.

The Kerr-McGee radiation areas consist of the Kerr-McGee Facility (Illinois Department of Nuclear Safety jurisdiction) and National Priorities List (NPL) areas in and around West Chicago, Illinois: (1) Reed-Keppler Park, (2) the West Chicago Regional Wastewater Treatment Plant (WTP), (3) residential areas, (4) Kress Creek, and (5) the West Branch of the DuPage River (included with the WTP or Kress Creek areas for the NPL listings). Chemicals of concern include radon, radium, thorium, uranium, antimony, arsenic, barium, boron, cadmium, fluoride, lead, manganese, nickel, nitrate, selenium, silver, vanadium, zinc, and possibly chromium and polychlorinated biphenyls (PCBs). Exposure pathways include the inhalation of contaminated dust and gases; the ingestion of dust, groundwater, soil, sediments, and surface water; and dermal contact with dust, sediments, soil, and surface water. Final rept. See also PB90-106089.

NTIS/DE95001091

38p

1994. LEAK: A source term generator for evaluating release rates from leaking vessels.

Author: Clinton JH

Oak Ridge National Lab., TN.

Sponsored by Department of Energy, Washington, DC.

An interactive computer code for estimating the rate of release of any one of several materials from a leaking tank or broken pipe leading from a tank is presented. It is generally assumed that the material in the tank is liquid. Materials included in the data base are acetonitrile, ammonia, carbon tetrachloride, chlorine, chlorine trifluoride, fluorine, hydrogen fluoride, nitric acid, nitrogen tetroxide, sodium hydroxide, sulfur hexafluoride, sulfuric acid, and uranium hexafluoride. Materials that exist only as liquid and/or vapor over expected ranges of temperature and pressure can easily be added to the data base file. The Fortran source code for LEAK and the data file are included with this report. (ERA citation 19:033861)

NTIS/DE94008814

14p

1993. Calcining process emission screening test for polychlorinated dibenzodioxins.

Author: Hartenstein SD

Westinghouse Idaho Nuclear Co., Inc., Idaho Falls.

Supporting Agency: Department of Energy, Washington, DC.

Since 1963, the Idaho Chemical Processing Plant (ICPP) at the Idaho National Engineering Laboratory has been using fluidized-bed technology to convert high-level radioactive liquid waste into a granular solid for interim storage before eventual long-term storage. The calcining process uses kerosene, oxygen, air and a cooling jacket to maintain the temperature of the fluidized bed at approximately 400 C. The solids are moved to storage bins and the combustion gases and fine particles are swept from the bed to an atmospheric protection system. This atmospheric protection system includes a cyclone to collect larger particles; a nitric acid scrubber to cool gases and collect small particles; a condenser to reduce water content; silica gel beds to adsorb volatile ruthenium, water, and hydrocarbons; and a series of high efficiency particulate air (HEPA) filters to collect minute particles. The calcination process solidifies waste solutions containing molar levels of acid, nitrate, fluoride, zirconium, [abstract truncated]

NTIS/DE93013210

5p

1993. Evaluation of possible biological effects from exposure to gaseous SF6 breakdown products.

Authors:
Griffin GD
Sauers I
James DR

Oak Ridge National Lab., TN.

Supporting Agency: Department of Energy, Washington, DC.

A variety of chemical byproducts including SOF(sub 2), SO(sub 2)F(sub 2), SF(sub 4), HF, SO(sub 2), etc. are produced at varying concentrations by electrical arcs, sparks or corona discharge in SF(sub 6); most of the byproducts are toxic to some degree. Using a cell culture system, we have studied the toxicity of individual byproduct gases, as well as electrically decomposed SF(sub 6). The toxic potency of various byproducts can be compared, using this cellular assay. The animal toxicological data for these gases, although sparse, is also reviewed. The rationale for selection of various byproduct gases as monitors for evaluating the hazard potential of decomposed SF(sub 6) is discussed. (ERA citation 18:024925) International symposium on high voltage engineering (8th), Yokohama (Japan), 23-27 Aug 1993.

NTIS/DE93006539

45p

1992. Principles of measurement and system specifications for continuous vent stack sampling.

Authors:
Sheller AJ
Saraceno AJ
Orlett MJ
Zonner LA

Martin Marietta Energy Systems, Inc,. Piketon, OH.

Supporting Agency: Department of Energy, Washington, DC.

Continuous vent stack sampling for monitoring of radionuclide discharges is required under the National Emission Standards for Hazardous Air Pollutants (NESHAP) regulations of the Clean Air Act. At Portsmouth, fourteen vent stacks with the potential for release of radioactive discharges that could cause an effective dose equivalent of greater than 0.1 mrem/yr. to the public have continuous samplers installed to measure radioactive discharges. A continuous sampler consists of a point source radionuclide extraction system that includes an isokinetic probe, collection traps, a pump and/or airjet, a sample flowmeter and a vent stack flow monitor. The system continuously withdraws a representative measured sample of stack gas which is passed through traps of activated alumina that is subsequently analyzed by the Analytical Services Laboratory for total uranium, (sup 235)U, (sup 99)Tc and reactive fluoride. Systems for continuous sampling must meet a number of criteria and specifications to ensure qua [abstract truncated]

NTIS/DE91017791

23p

1991. Method of processing alkaline fluoride liquid waste which contains metal ions and oil.

Authors:
Nishimoto T
Sasaki T
Sugisawa M

Oak Ridge Y-12 Plant, TN.

Alkaline fluoride liquid waste containing metal ions and oil is neutralized by addition of hydrogen fluoride, and then oil is removed; metal ions are absorbed and removed using chelate resin, and then the liquid waste is separated into alkali and hydrogen fluoride, and regenerated and recovered by an ion-exchange membrane electrodialyzer which consists of bipolar membranes, anion exchange membranes and cation exchange membranes. The hydrogen fluoride which is added to the above liquid part of the recovered hydrogen fluoride. 2 figs. Translation of Japanese Patent Application No. 01-130783, May 23, 1989..

NTIS/DE92004452

44p

1991. External quality control in ground-water sampling and analysis at the Hanford Site.

Authors:
Hall SH
Juracich SP

Battelle Pacific Northwest Labs., Richland, WA.

Supporting Agency: Department of Energy, Washington, DC.

At the US Department of Energy's Hanford Site, external Quality Control (QC) for ground-water monitoring is extensive and has included routine submittal of intra- and interlaboratory duplicate samples, blind samples, and several kinds of blank samples. Examination of the resulting QC data for nine of the constituents found in ground water at the Hanford Site shows that the quality of analysis has generally been within the expectations of precision and accuracy that have been established by the US Environmental Protection Agency (EPA). The constituents subjected to review were nitrate, chromium, sodium, fluoride, carbon tetrachloride, tritium, ammonium, trichloroethylene, and cyanide. Of these, the fluoride measurements were notable exceptions and were poor by EPA standards. The review has shown that interlaboratory analysis of duplicate samples yields the most useful QC data for evaluating laboratory performance in determining commonly encountered constituents. For rarely encountered constituent [abstract truncated]

NTIS/DE91015663

61p

1991. Biological studies in the impact zone of the Liquefied Gaseous Fuels Spill Test Facility in Frenchman Flat, Nevada.

Authors:
Hunter RB
Saethre MB
Medica PA
Greger PD
Romney EM

Reynolds Electrical and Engineering Co., Inc., Las Vegas, NV.

Sponsored by Department of Energy, Washington, DC.

Desert shrubs and rodents were monitored downwind of the Department of Energy Liquefied Gaseous Fuels Spill Test Facility (LGF), which is situated on a dry lake bed (playa). Plants were censused in 1981 and 1986 through 1990; rodent survival was measured from 1986 through 1990. During that time there were no apparent effects of the spill tests on animals or plants off the edge of the playa, which extends more than 2.5 kilometers from the facility. Plant populations increased in volume from 1981 through 1986, then declined precipitously during drought in 1989 and 1990. Rodent populations also declined during the drought. Some effects of spilled hydrogen fluoride gas were seen on plants growing on manmade mounds on the playa surface. Animal and bird species seen in the vicinity of the LGF are also reported. 11 refs., 10 figs., 16 tabs.

NTIS/DE91017447

18p

1991. Reliability performance testing of totally encapsulating chemical protective suits.

Authors:
Johnson JS
Swearengen PM

Lawrence Livermore National Lab., CA.

The need to assure a high degree of reliability for totally encapsulating chemical protective (TECP) suits has been recognized by Lawrence Livermore National Laboratory's (LLNL) Hazards Control Department for some time. We have conducted two series of worst-case TECP suit exposure tests to hydrogen fluoride (HF) as tag-along experiments at the DOE Liquid Gaseous Fuels Spill Test Facility, Frenchmen Flat Basin, Nevada Test Site 2,3,4. Results from these tests indicated additional experiments are necessary to adequately evaluate TECP suit performance to HF. Our tag-along experience also demonstrated the need for a separate Small Scale Spill (S(sup 3)) Facility for carrying out TECP suit exposures, as well as other performance evaluations of chemical emergency response equipment. Financial support from a large number of private sector manufacturers and users of HF, as well as the DOE Collaborative Research and Development Program and LLNL, has been obtained to continue our study of TECP suit perfor [abstract truncated]

NTIS/NUREG-1391

18p

1991. Chemical Toxicity of Uranium Hexafluoride Compared to Acute Effects of Radiation.

Author: McGuire SA

Nuclear Regulatory Commission, Washington, DC. Office of Nuclear Regulatory Research.

The chemical effects from acute exposures to uranium hexafluoride are compared to the nonstochastic effects from acute radiation doses of 25 rems to the whole body and 300 rems to the thyroid. The analysis concludes that an intake of about 10 mg of uranium in soluble form is roughly comparable, in terms of early effects, to an acute whole body dose of 25 rems because both are just below the threshold for significant nonstochastic effects. Similarly, an exposure to hydrogen fluoride at a concentration of 25 mg/cu m for 30 minutes is roughly comparable because there would be no significant nonstochastic effects. For times t other than 30 minutes, the concentration C of hydrogen fluoride considered to have the same effect can be calculated using a quadratic equation: C = 25 mg/cu m (30 min/t)(sup 0.5). The purpose of these analyses is to provide information for developing design and siting guidelines based on chemical toxicity for enrichment plants using uranium hexafluoride. These guidelines are t [abstract truncated]

NTIS/DE93601641

U.S. Sales Only.

18p

1991. Study on the retention of enriched UO(sub 2)F(sub 2) in the mouse and its radiogenotoxicological effects.

Authors:
Hu Q
Zhu S

China Nuclear Information Centre, Beijing.

The study on toxicological effects of enriched UO(sub 2)F(sub 2) was undertaken in purebred BALB/c male mice to examine: (a) the retention in body; (b) the testicular clearance; (c) the effect of sperm abnormality; (d) the effect of chromosomal aberrations in spermatogonia and primary spermatocytes; and (e) the effect of DNA damage in germ cells in various spermiogenic stages. Results show that enriched UO(sub 2)F(sub 2) mainly deposited in the kidneys, then the skeleton and liver. The amount of enriched UO(sub 2)F(sub 2) depositing in other tissues was small. Enriched UO(sub 2)F(sub 2) was similar to the natural uranium in transference and retention in the body. The testis had efficient clearance of enriched UO(sub 2)F(sub 2). Enriched UO(sub 2)F(sub 2) could result in sperm abnormality. Even with the same treating does but at different treating time the rates of sperm abnormality were different. Enriched UO(sub 2)F(sub 2) could result in chromosomal aberrations in spermatogonia and primary spe [abstract truncated]

NTIS/DE92015322

299p

1990. F-Area seepage basins, groundwater quality assessment report, first quarter 1990.

Westinghouse Savannah River Co., Aiken, SC.

Supporting Agency: Department of Energy, Washington, DC.

During the first quarter of 1990, wells which make up the F-Area Seepage Basins (F-HWMF) monitoring network were sampled. Laboratory analyses were performed to measure levels of hazardous constituents, indicator parameters, tritium, gross alpha, and nonvolatile beta. The primary contaminants observed at wells monitoring the F-Area Seepage Basins are tritium, nitrate, cadmium, lead, total radium, gross alpha, and nonvolatile beta. Concentrations of at least one of the following constituents: tritium, nitrate, total radium, gross alpha, cadmium, lead, tetrachloroethylene, nonvolatile beta, endrin, lindane, barium, fluoride, mercury, and trichlorethylene in excess of the primary drinking water standard (PDWS) were observed in at least one well monitoring the F-Area Seepage Basins. Tritium concentrations above the PDWS occur in forty-four of the fifty-nine (75%) groundwater monitoring wells. Nitrate concentrations above the PDWS occur in thirty-four of the fifty-nine (59%) groundwater wells. The rad [abstract truncated]

NTIS/DE92017499

19p

1990. Behavior and control of ruthenium during operation of the New Waste Calcining Facility at the Idaho Chemical Processing Plant.

Author: Christian JD

Westinghouse Idaho Nuclear Co., Inc., Idaho Falls.

Supporting Agency: Department of Energy, Washington, DC.

The New Waste Calcining Facility (NWCF) processes acidic fluoride and nitrate high level liquid wastes, converting them to granular solids in a fluidized bed by internal combustion of kerosene. The off gases pass through a venturi scrubber, silica gel bed, and HEPA filters. Normally, less than 4 (mu)Ci (sup 106)Ru/day are released in the form of particulate material to the stack. Some operations can cause small, but noticeable increases in (sup 106)Ru releases. Although resulting lung doses are extremely small, because of the public perceptions and ALARA principles controls have been implemented to prevent any releases significantly above normal. Evaluations were made of ruthenium behavior during the various operations in the NWCF and parameters that affect its volatility. The results of the evaluations and recommended controls to prevent ruthenium releases, which are described in detail, are as follows. Dissolution of calciner bed in boiling 13 M HNO(sub 3) with the silica gel beds bypassed res [abstract truncated]

NTIS/DE89008970

Portions of this document are illegible in microfiche products.

157p

1989. Health Risks from Mixtures of Radionuclides and Chemicals in Drinking Water.

Authors:
Jones TD
Owen BA

Oak Ridge National Lab., TN.

The Food and Drug Administration (FDA) has pioneered a ''generally recognized as safe,'' or GRAS, concept. In this study, we propose to build on that infrastructure somewhat differently but in a way consistent with the general intent of the FDA. As three examples of potential GRAS-equivalent indexes, we explore: hypothetically pure utility drinking water containing fluoride (1 ppM) and chlorination residue products consumed at a personal ingestion rate of 2 L/d; consumption of one reference metal and 2 L/d and the 40-mrem annual natural terrestrial radiation background as described by the US National Academy of Sciences (NAS 1980). On the basis of conventional QRA models and the proposed relative method scaled to the described GRAS-equivalent indexes, we demonstrate techniques of relative comparisons to enhance absolute or QRA models and simultaneously to implement a ''reality check.'' Comparisons permit the decision maker to draw meaningful conclusions to better allocate resources. We demonstra [abstract truncated]

NTIS/DE89011306

Portions of this document are illegible in microfiche products.

85p

1989. Evaluation of Chemical Sensors for In Situ Ground-Water Monitoring at the Hanford Site.

Authors:
Murphy EM
Hostetler DD

Battelle Pacific Northwest Labs., Richland, WA.

Supporting Agency: Department of Energy, Washington, DC.

This report documents a preliminary review and evaluation of instrument systems and sensors that may be used to detect ground-water contaminants in situ at the Hanford Site. Three topics are covered in this report: (1) identification of a group of priority contaminants at Hanford that could be monitored in situ, (2) a review of current instrument systems and sensors for environmental monitoring, and (3) an evaluation of instrument systems that could be used to monitor Hanford contaminants. Thirteen priority contaminants were identified in Hanford ground water, including carbon tetrachloride and six related chlorinated hydrocarbons, cyanide, methyl ethyl ketone, chromium (VI), fluoride, nitrate, and uranium. Based on transduction principles, chemical sensors were divided into four classes, ten specific types of instrument systems were considered: fluorescence spectroscopy, surface-enhanced Raman spectroscopy (SERS), spark excitation-fiber optic spectrochemical emission sensor (FOSES), chemical op [abstract truncated]

NTIS/DE89014924

Portions of this document are illegible in microfiche products.

11p

1989. Integrated Enviromental Monitoring Program at a US Nuclear Research Facility.

Author: Gray RH

Battelle Pacific Northwest Labs., Richland, WA.

Water quality issues are key components of a comprehensive environmental monitoring and surveillance program. In addition to monitoring radioactivity and chemicals in surface and ground water, the program monitors air, foodstuffs, wildlife, soil and natural vegetation. Population numbers of key wildlife species are also determined, usually during the breeding season. In 1987, measured Hanford Site perimeter concentrations of airborne radionuclides were below applicable guidelines. Tritium and nitrate continued to be the most widespread constituents in onsite ground water. Chromium, cyanide, fluoride, and carbon tetrachloride were found in ground-water wells near operating areas. Concentrations of radionuclides identified at a municipal water intake on the Columbia River were below limits established for drinking water. Foodstuffs irrigated with river water taken downstream of the site showed low levels of radionuclides that were similar to concentrations found in foodstuffs not irrigated with Co [abstract truncated]

NTIS/DE90617516

U.S. Sales Only.

174p

1989. (Contribution to the study of uranium migration and some trace elements in solution from Pocos de Caldas uranium mining).

Author: Zenaro R

Pontificia Univ. Catolica do Rio de Janeiro (Brazil). Dept. de Quimica.

It was studied the chemical composition of ground water from four boreholes as a contribution to the hydrogeochemical studies in the Pocos de Caldas uranium mining. Methods for water analyses were selected and optimized in order to determine the main anions, specially the ones which form stable complexes with uranium ions. Fluoride and chloride were determined by potentiometry; phosphate, nitrate and silicate by spectrophotometry. Cations were determined by atomic absorption spectrophotometry flame emission and argon plasma emission excited by continuous current arch (DCP). Uranium was determined by fluorimetry with a concentration range from 3 to 7 ppb and its distribution calculated among the different species into solution through the measures of pH, Eh, anion amounts and stability of their respective complexes. (author). (Atomindex citation 21:023320) Thesis. In Portuguese.

NTIS/DE89008246

Portions of this document are illegible in microfiche products.

15p

1989. Monitoring for Potential Environmental Problems at a Nuclear Research Facility at Hanford, Washington, USA.

Author: Gray RH

Battelle Pacific Northwest Labs., Richland, WA.

Supporting Agency: Department of Energy, Washington, DC.

Objectives are to detect and assess potential impacts of site operations on air, surface and ground water, foodstuffs, fish, wildlife, soil and vegetation. Data from monitoring efforts are used to calculate the overall radiological dose to humans working onsite or residing in nearby communities. In 1987, measured Hanford Site perimeter concentrations of airborne radionuclides were below applicable DOE and Environmental Protection Agency guidelines. Tritium and nitrate continued to be the most widespread constituents in onsite ground water. Chromium, cyanide, fluoride, and carbon tetrachloride were found in ground-water wells near operating areas. Concentrations of radionuclide and nonradiological water quality in the Columbia River were in compliance with applicable standards. Foodstuffs irrigated with river water taken downstream of the Site showed low levels of radionuclides that were similar to concentrations found in foodstuffs from control areas not irrigated with Columbia River water. Low [abstract truncated]
 
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