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C8 or C-8: PFOA is perfluorooctanoic acid and is sometimes called C8. It is a man-made chemical and does not occur naturally in the environment. The "PFOA" acronym is used to indicate not only perfluorooctanoic acid itself, but also its principal salts.
The PFOA derivative of greatest concern and most wide spread use is the ammonium salt (
Ammonium perfluorooctanoate) commonly known as C8, C-8, or APFO and the chemical of concern in the Class Action suit in Ohio.

Ammonium perfluorooctanoate (APFO or C8)
CAS No. 3825-26-1. Molecular formula:

Perfluorooctanoic acid (PFOA or C8)
CAS No: 335-67-1
. Molecular formula:

The DuPont site where APFO is used as a reaction aid is the Washington Works (Route 892, Washington, West Virginia 26181) located along the Ohio River approximately seven miles southwest of Parkersburg, West Virginia.

The Little Hocking Water Association well field is located in Ohio on the north side of the Ohio River immediately across from the Washington Works facility. Consumers of this drinking water have brought a Class Action suit against the Association and DuPont for the contamination of their drinking water with DuPont's APFO, which residents and media refer to as C8.

PFOA is used as a processing aid in the manufacture of fluoropolymers to produce hundreds of items such as non-stick surfaces on cookware (TEFLON), protective finishes on carpets (SCOTCHGUARD, STAINMASTER), clothing (GORE-TEX), and the weather-resistant barrier sheeting used on homes under the exterior siding (TYVEK).

 

Online at: http://www.delawareonline.com/newsjournal/local/2004/04/15fearforthehealt.html

April 15, 2004

The News Journal (Delaware)

Fear for the health of a river
'Red flag' raised over what plant dumps into water

By JEFF MONTGOMERY
Staff reporter

For nearly 30 years, the DuPont Co. has marketed its Chambers Works wastewater plant as a treatment-for-hire operation, taking in hazardous liquids from across the continent to boost revenue at its chemical complex in Deepwater, N.J.

Now an Army proposal to ship chemical-weapons disposal waste from Indiana to the plant is highlighting its status as one of the nation's top sources of toxic water discharges, according to Environmental Protection Agency records.

DuPont wants an Army contract to treat up to 4 million gallons of caustic wastewater containing chemicals left over after neutralization of VX nerve agent, one of the world's deadliest chemical weapons. The project would replace a disposal plan the Army abandoned last year in Ohio in the face of community opposition.

Despite DuPont's patented method for scrubbing wastewater with carbon and microbes, environmental groups have said the Secure Environmental Treatment Unit at the foot of the Delaware Memorial Bridge symbolizes weaknesses in the Clean Water Act. That law, members of state and national environmental groups said, lets some wastewater plants serve as "pollution sinks," releasing toxic and sometimes obscure chemicals that may be overlooked or go unmentioned in public reviews and reports.

"I think that a big red flag is flying above DuPont Chambers Works right now, and frankly, it's begging for an investigation into what they are currently discharging into the river, and what they propose to discharge into the river," said Maya van Rossum, who directs the Delaware Riverkeeper Network, an environmental group.

Paul D. Schwartz, national policy director for the environmental group Clean Water Action, said wastewater plants are required to identify on permits any pollutants they expect to discharge from their plants. In some cases, however, day-to-day releases of chemicals may go unmonitored because concentrations are low, they are unmentioned on federal "priority pollutant" lists or they have yet to be studied for toxic effects.

The governors of Delaware and New Jersey urged the Army last week to reconsider its chemical weapons waste plan, pointing to evidence that Chambers Works would simply dilute and discharge two compounds without a clear understanding of the effect on the river.

Delaware Water Resources Director Kevin C. Donnelly said Wednesday that a Delaware River Basin Commission permit for DuPont's operation appears to bar the new VX waste enterprise without a full permit review. DuPont officials said the company could begin the operation without an explicit permit approval.

But Donnelly said a 1991 commission approval for DuPont's operation prohibits the company from releasing any pollutants to the river if they come from outside the river basin - land that drains into the Delaware or its tributaries. State officials last week pointed out that Chambers Works would merely dilute in the river as much as 2.3 tons of the Army wastes per day.

"Dilution does not equal removal," said Donnelly, of the Delaware Department of Natural Resources and Environmental Control.

Officials in Delaware also are examining their authority to influence activities at Chambers Works. Although the plant is in New Jersey, its treated wastewater exits from a pipe at the bottom of the river well inside Delaware.

Delaware regulators are concerned about a DuPont proposal to update its federal water discharge permit to treat a wider range of new industrial pollutants including chemical weapons disposal waste.

"It's a very significant issue for Delaware and New Jersey, and it's something we need to catch up on," Donnelly said. "Millions of gallons a day get handled and treated, and I think all of us are interested in taking a closer look."

Chambers Works already handles a large percentage of industrial wastewater generated in New Jersey, according to federal records.

"We've been doing this for 25 years. Industries and companies send us their wastewater from all over North America," said Todd Owens, a DuPont chemical engineer at the plant. "It's always been known that we're fairly unique in terms of our technology."

But Donnelly said state officials have not closely examined the discharges, or exercised authority over the New Jersey plant's releases into the river. Delaware's state line begins at the edge of the water on New Jersey's side of the river.

Major source of pollution

EPA reports show Chambers Works has discharged as much as 3.8 million pounds of toxic pollutants yearly since 1989. Releases range from algae-promoting nitrate compounds to substances that could cause cancer, developmental and reproductive disorders or other problems in humans, animals or aquatic life.

Annual totals have varied widely. Output in 2001 was less than 1.2 million pounds, making the operation the nation's 39th largest source of toxic pollution to water.

Nitrate compounds, which can contribute to clouding of the water and reduction in oxygen levels, which support aquatic life, accounted for the largest share of pollution releases in 2001.

In 1997, Public Interest Research Group said Chambers Works was the largest discharger along the Delaware River of toxic metals and reproductive toxins - substances such as toluene, mercury and some pesticides that can affect fertility or reproduction in humans and animals. At the time, the New Jersey site was the nation's 14th largest source of toxic water releases overall. A year later, it was 11th on the list.

By comparison, the Motiva Enterprises Delaware City Refinery reported releasing 47,000 pounds of toxic pollutants into the river in 2001, less than 5 percent of the Chambers Works release.

"This whole idea that you can sell the capacity at a sewage treatment plant to handle a variety of contaminant loads, so the plants become pollution sinks for stuff that's politically difficult or expensive to handle elsewhere is outrageous," Clean Water Action's Schwartz said.

Anthony Farina, a spokesman for DuPont, said the Chambers Works wastewater system is widely known for its capabilities, with many of its customers found in New Jersey or neighboring states.
"They seek out our assistance because they simply do not have the technology or capabilities to treat their wastewater safely or effectively," he said.

Several environmental organizations said many potentially hazardous pollutants never show up on routine public reports for Chambers Works or other wastewater operations.

DuPont increased its releases of one such chemical, called ammonium perfluorooctanoate, or C-8, to the river after lawsuits and health concerns prompted the company to reduce discharges of the chemical at a DuPont site in West Virginia.

The EPA last year said "potential toxicity concerns" about C-8 and other chemicals in its class warranted a major study. Contributing to the concerns were claims - disputed by the company - that company operations had polluted drinking water supplies and sickened livestock.

Owens said DuPont had kept New Jersey informed about the C-8 releases to the Delaware River. But that chemical and others are absent from regular public reports because the compounds are unregulated or untested for toxicity or the chemicals are diluted to levels that make monitoring unnecessary.

"If the states are not going in and doing aggressive auditing, then we're relying on the good graces of the discharger," said Schwartz of Clean Water Action. "The public is really left out of the loop. The only time the public has the capacity to challenge the terms of the permit is when it comes due and is up for renewal."

A DuPont voluntary disclosure document filed with the EPA in early 2001 noted Chambers Works captures about 30 percent of the C-8 processed through its wastewater plant. About five tons of C-8 was discharged into the river in 1999, and four tons were captured for disposal in the Deepwater landfill. More recent estimates were unavailable.

Expanded operations planned

DuPont's proposed plan to treat wastes from the Army nerve agent disposal program reflects new ambitions for the treatment plant. Company officials said they want to expand the already wide range of industries their plant can serve under their five-year National Pollution Discharge Elimination System permit, which ended its regular cycle in January. Operations have continued under an extension of the older permit while New Jersey considers a new plan that was submitted last year.

Owens said the company identified in the new permit application additional industries it will serve as well as additional compounds that could be discharged.

Chemical weapons "demilitarization" wastes are among the industries DuPont wants to add to the permit, Owens said.

Treated wastewater from Chambers Works, company officials said, is harmless even to minnows and water fleas, based on company scans for toxicity in the plant's output.

"We think it's positive, in appropriate circumstances, that DuPont is making available its waste treatment capacity," to other industries, said New Jersey Department of Environmental Protection Commissioner Bradley Campbell.

Campbell said his agency, working closely with Delaware regulators, is considering tighter restrictions on Chambers Works that might take into account the combined effects of chemicals discharged by the plant.

"We want to make sure that neither New Jersey nor the Delaware River are put at risk or treated as the disposal area of first resort," Campbell said.

Once a gunpowder plant

Chambers Works, which covers 1,455 acres, began as a smokeless gunpowder plant in 1892 and expanded into dyes, freon, Teflon, tetraethyl lead and other compounds. During World War II, researchers at Deepwater carried out work critical to the development of the first atomic bombs. The site opened its current wastewater plant in 1976. In recent years, it expanded an above-ground hazardous waste landfill that takes hazardous sludge from the wastewater plant.

DNREC's review of the Army's waste disposal plan focused heavily on risks involved in releasing to the river two phosphorus compounds, ethyl methylphosphonic acid and methylphosphonic acid.

A DuPont study released in March found the two chemicals "will have no aquatic toxicological impact." But state officials said little is known about their effect in the environment, and questioned the reports issued on the company's behalf.

"DuPont's assessment of the potential impacts associated with the discharge was neither complete nor conservative," one DNREC study pointed out.

Donnelly said the latest proposal may trigger a review of an earlier company decision to treat wastes from a mustard gas stockpile in Aberdeen, Md.

Paul F. Walker, with Global Green USA, an international environmental group, said the phosphonic acids probably represent little long-term risk to the river.

"It's not necessarily a bad idea to ship to DuPont, but you just have to demand heavy oversight, complete transparency and access to data on a timely basis, to build stakeholder confidence," Walker said.

The Delaware Nature Society said it opposes importing waste. "We ... see no need to further degrade river quality by processing waste from other states," said executive director Michael E. Riska.

Reach Jeff Montgomery at 678-4277 or jmontgomery@delawareonline.com.