Fluoride
Reports from the National Technical Information Service (NTIS)
1986-1987
 
 

Return to Reports Page

Due to the number of reports, the following
are the categories we present them.
(Note: these reports were cited on Toxline at Toxnet in April 2005)
Fluoride (all reports except Canada)
Fluoride: CANADA
Fluoride in the
Nuclear Industry
Note: many of the
Canadian communities
cited in these reports
border the US.
-
-
Note: this is a selected
list of reports.

NTIS Reports can be ordered by: phone at 1-800-553-NTIS (U.S. customers); (703)605-6000 (other countries); fax at (703)605-6900; and email at orders@ntis.gov. NTIS is located at 5285 Port Royal Road, Springfield, VA, 22161, USA.

Order Number

Source Number

Date Published / Title / Author & Affiliation / Sponsor Agency Abstract /Keywords

NTIS/PB87-170817

89p

1987. Analysis of Costs for the Treatment of Dental Fluorosis.

Authors:
Collins E
Segreto V
Martin H
Dickson H

Texas Univ. Health Science Center at San Antonio.

The research project was initiated to conduct a cost/benefit analysis for those communities whose fluoride levels exceed two times the optimum and to determine the economic impact of defluoridating community drinking water. The initial data used in this study were from a project conducted by the University of Texas at San Antonio for the Environmental Protection Agency's Health Effect Research Laboratory. This earlier project was used to select representative cases of fluorosis from each community with water fluoride levels from optimum to 4.0 ppm. The clinical findings of each case were presented to a panel of clinical practitioners for diagnosis of the extent of cosmetic deformity and dental dysfunctional effects present in the dentition as a result of excessive fluoride. Cost estimates were made for the remedial care proposed for each subject by each panel member. Using these data an evaluation was made of the beneficial effects of optimum water fluoride levels (savings from caries reduction) [abstract truncated]

NTIS/PB90-109273

13p

1987. Health Assessment for Northern Engraving Company, Sparta, Wisconsin, Region 5. CERCLIS No. WID980684674.

Agency for Toxic Substances and Disease Registry, Atlanta, GA.

The Northern Engraving Corporation (NEC) site is located in Sparta, Monroe County, Wisconsin. Groundwater on the site is contaminated with copper, chromium, iron, zinc, nickel, and fluoride, some at levels which could pose a public health threat if the groundwater from the site is used for drinking or other consumption purposes. An assessment of the health threat posed by contaminants in residential wells was not possible because the data for these items were either incomplete or unavailable. The major contaminants found in groundwater at the NEC site were reported at the following maximum levels: copper, 1.23 mg/l; nickel, 4.33 mg/l; aluminum, 5.3 mg/l; iron, 11.25 mg/l; and fluoride, 78.73 mg/l. Organics analysis on groundwater samples collected at the site found trace levels of vinyl chloride; trans-1,2-dichloroethylene and bromodichloromethane were present in one well (monitoring Well B). Under present conditions, the site does not appear to pose a significant public health risk. Final rept.

NTIS/PB87-227047

125p

1987. Prevention Reference Manual: Chemical Specific. Volume 1. Control of Accidental Releases of Hydrogen Fluoride (SCAQMD) (South Coast Air Quality Management District).

Authors:
Davis DS
DeWolf GB
Quass JD

Radian Corp., Austin, TX.

Supporting Agency: Environmental Protection Agency, Research Triangle Park, NC. Air and Energy Engineering Research Lab.

The manual summarizes technical information that will assist in identifying and controlling hydrogen fluoride release hazards specific to the South Coast Air Quality Management District (SCAQMD) of southern California. The SCAQMD has considered a strategy for reducing the risk of a major accidental air release of toxic chemicals. The strategy includes monitoring the storage, handling, and use of certain chemicals and provides guidance to industry and communities. Anhydrous hydrogen fluoride, a corrosive liquid that boils at room temperature, rapidly absorbs moisture to form highly corrosive hydrofluoric acid. Hydrogen fluoride gas has an IDLH (immediately dangerous to life and health) concentration of 20 ppm, which makes it a substantial acute toxic hazard. Reducing the risk associated with an accidental release of hydrogen fluoride involves identifying some of the potential causes of accidental releases that apply to the processes that use hydrogen fluoride in the SCAQMD. The manual identifies [abstract truncated]

Order Number: NTIS/AD-A187 292/8

7p

1987. Effects of Sodium Fluoride on Uptake of T-2 Mycotoxin in Cultured Cells,

Authors:
Trusal LR
Martin LJ

Army Medical Research Inst. of Infectious Diseases, Fort Detrick, MD.

The authors examined the effect of sodium fluoride on uptake of tritium-labeled T-2 toxin (molecules of toxin/cell) in Chinese hamster ovary (CHO) and African green monkey kidney (VERO) cells. Correlations were made to temperature (22 and 37 C) and toxin concentration (0.001 and 0.01 ug/ml) over time (0-180 min). As expected, toxin uptake increased in uptake increased in both cell types with increasing time and temperature. VERO cells exhibited significant (P<0.05) increases in the rate (i.e. slope) of toxin uptake under all parameters, while the rate of toxin uptake in both cell types was generally greater at 37 C. compared to 22 C. The rate of equilibrium was affected by both temperature and sodium fluoride. At 37 C toxin uptake plateaued by 30 min in the presence of sodium fluoride. At 22 C the rate of toxin update was slower, with or without sodium fluoride present. Statistical analysis of individual time points along the curve demonstrated that sodium fluoride significantly increased cel [abstract truncated]

NTIS/AD-A187 062/5

36p

1986. Uptake of T-2 Mycotoxin in Cultured Cells. Relationship to Sodium Fluoride and Cell Type,

Authors:
Trusal LR
Martin LJ

Army Medical Research Inst. of Infectious Diseases, Fort Detrick, MD.

The authors examined the effect of sodium fluoride on uptake of tritium-labeled T-2 toxin (molecules/cell) in Chinese hamster ovary (CHO) and African green monkey kidney (VERO) cells. Correlations were made to temperature and toxin concentration over time. As expected, toxin uptake increased in both cell types with increasing time and temperature. Under all parameters, VERO cells exhibited significant increases in the rate of toxin uptake. The rate of equilibrium was affected by both temperature and sodium fluoride. Statistical analysis of individual time points along the curve demonstrated that sodium fluoride significantly increased cell-associated toxin at most time points. Analysis of the slopes of uptake curves from 0 to 20 min indicated significant (p<0.05) differences in the rates of T-2 uptake in both cell types and toxin doses in the presence of sodium fluoride. The increase in toxin uptake in the presence of sodium fluoride was not due to altered cell membrane permeability caused by [abstract truncated]

NTIS/PB87-204954

30p

1987. Health Hazard Evaluation Report HETA 84-496-1766, Applied Plastics, Slocum, Rhode Island,

Authors:
Keenlyside RA
House LA
Stoekel M
Durand JM

National Inst. for Occupational Safety and Health, Cincinnati, OH. Hazard Evaluations and Technical Assistance Branch.

In response to a request from the owners of Applied Plastics, Inc. (SIC-3079), Slocum, Rhode Island, an investigation was made of possible cases of polymer fume fever among workers complaining of fever, chills, fatigue, shortness of breath, nausea, musculoskeletal pain and headache. Urinary fluoride (16984-48-8) levels measured in preshift samples ranged from 0.3 milligrams/gram (mg/g) to 1.5 mg/g and from 0.2 mg/g to 1.0 mg/g in postshift samples. Breathing zone samples showed low levels of toluene (108883) and most had a trace amount of hexane equivalents. All levels of toxic substances were well below permissible exposure limits. The authors conclude that even though the environmental and medical studies did not demonstrate high exposure levels or absorption of fumes, workers did demonstrate sometimes incapacitating symptoms of polymer fume fever. Based on this, the authors recommend changes in work practices, improved ventilation, closer attention to no smoking policies, and improved personal

NTIS/PB88-159967

55p

1987. Superfund Record of Decision (EPA Region 4): Palmetto Wood Preserving, Dixiana, Lexington County, South Carolina, (First Remedial Action), September 1987.

Environmental Protection Agency, Washington, DC.

The Palmetto Wood Preserving (PWP) Site is located in the rural community of Dixiana, South Carolina. The 5-acre site is a decommissioned wood preserving facility which operated between 1963 and 1985. PWP began operating in 1963 using a fluoride-chromate arsenate-phenol (FCAP) and an acid-copper-chromate (ACC) process. In 1980, Eastern Forest Products took over and switched to a chromate-copper-arsenate (CCA) process. Operations consisted of impregnating wood with a CCA solution under high pressure, and allowing the wood to drip-dry under normal conditions. Beginning in December 1981, the South Carolina Department of Health and Environmental Control (SCDHEC) received complaints of green liquids running off the PWP site during heavy rainfall. Subsequent soil sampling conducted by SCDHEC indicated the presence of high concentrations of chromium. Pentachlorophenol (PCP) and dinitrophenol residues were also detected. Well water sampling showed no evidence of contamination. In April 1983, a private w [abstract truncated]

NTIS/PB88-220983

162p

Portions of this document are not fully legible.

1987. Superfund Record of Decision (EPA Region 8): Central Citylear Creek, Colorado (First Remedial Action), September 1987.

Environmental Protection Agency, Washington, DC.

The focus is on five abandoned mines/tunnels proximal to the cities of Idaho Springs, Black Hawk and Central City and the influence of acid mine drainage from those tunnels on adjacent stream courses. Surface water contamination results from acid mine drainage emanating from the five tunnels and from seepage of ground water through tailings piles both proximal to these tunnels and along stream courses. Approximately 1,200 lbs per day of dissolved and suspended metals are discharged to the Clear Creek drainage from the five mine tunnels. These dissolved and suspended metal loadings have resulted in a significant depletion of aquatic life and have potential impact to sediments and downstream users of surface and ground water. There are ten contaminants of concern including aluminum, arsenic, cadmium, chromium, copper, fluoride, lead, manganese, nickel, silver and zinc. Interim remedies are described. Final rept.

NTIS/DE88001369

Portions of this document are illegible in microfiche products.

93p

1987. Hydrofluoric Acid Spill Area: Environmental Information Document.

Authors:
Huber LA
Bledsoe HW

Savannah River Lab., Aiken, SC.

Supporting Agency: Department of Energy, Washington, DC.

The Hydrofluoric Acid Spill Area is located in the Central Shops Area of the Savannah River Plant (SRP). It is uncertain if a spill occurred at this site or if contaminated soil or containers were buried here. Soil cores from the Hydrofluoric Acid Spill Area have not been collected or analyzed. Four groundwater monitoring wells were installed around the spill area in 1984 and have been sampled quarterly since early 1985. The potential impacts of lead and fluoride were assessed because of their measured groundwater concentrations. The closure options considered for the Hydrofluoric Acid Spill Area are waste removal and closure, no waste removal and closure, and no action. The predominant pathways for human exposure to chemical and/or radioactive constituents are through surface, subsurface, and atmospheric transport. Modeling calculations were made to determine the risk to human population via these general pathways for the three postulated closure options. An ecological assessment was conducted [abstract truncated]

NTIS/NTN87-0745

1p

1987. Removal of Hydrofluoric Acid from Gas Streams by Solid Sorbents.

Department of Energy, Washington, DC.

This citation summarizes a one-page announcement of technology available for utilization. Removal of hydrofluoric acid (HF) vapor from vent gas streams by reaction with solid, calcium-based sorbents has been investigated as an alternative to wet scrubbing (the standard technique). The dry process has the potential advantage of producing the same end product as the wet technique-calcium fluoride-without having the necessity of the intermediate aqueous slurry. The gas stream studied consisted of HF, water, and nitrogen. Limestone, marble, and quicklime were investigated as potential solid sorbents; only the quicklime was found to be satisfactory. Using quicklime particles slaked in a packed-bed reactor, nearly total HF removal was achieved with 90% calcium utilization efficiency. The current study results are based on benchscale testing using a one-inch-diameter packed-bed reactor. Potential uses include scrubbing of acidic vent gas streams. The technique is easily applied to small gas streams, pa

NTIS/TIB/A94-02538

274p

1987. (Biological methods for measuring air pollution effects for immission control approval procedures. Final report).

Author: Kostka-Rick R

Umweltbundesamt, Berlin (Germany, F.R.).

To establish biological testing methods of air pollutants within the scope of immission control approval procedures, bioindicator plants should be tested for their applicability and their evidence in routine cases. For this, over a period of three years, accumulative and reactive indicator plants were applied in the vicinity of fluoride-emitting source, for realizing knowledge, relevant for practice about the conditions of cultivation and exposure of the monitorplants, as well as methods of measuring and evaluation of the visual air pollution effects. The fluoride-content in grass (grass-exposure method) and the increasing-rate of leaf necrosis of sensitive gladiolus plants (var. Snow Princess) are strictly correlated with the immission-load-parameters of F-immissions-rate (SAM-method) and F-deposition-rate, when the observation periods were considered separately or at longer term average of one or more years. The individual development of the indicator plants, weather conditions and, rather dis [abstract truncated]

NTIS/OTS0515792

EPA/OTS; Doc #86-870001716

1987. GROUNDWATER QUALITY ASSESSMENT OF WASTE POND AREA AND BACKGROUND CONDITIONS

DAMES & MOORE


ALLIED SIGNAL INC
PHENOL (108-95-2)
ENVIRONMENTAL FATE
MONITORING

15 CAS Nos. including

16984-48-8 (Fluoride ion)

NTIS/OTS0517105

EPA/OTS; Doc #86-870002016

1987. PHASE II - HYDROGEOLOGICAL IMPACT ASSESSMENT - WASTE DISPOSAL FACILITIES

D'APPOLONIA CONSULTING ENG

Too many CAS Nos.; however, included is

16984-48-8 (Fluoride ion)

NTIS/AD-A183 698/0

199p

1987. Field Applicable Method to Reduce Dental Emergencies.

Authors:
Tinanoff N
Camosci D
Manwell M

Connecticut Univ. Health Center, Farmington.

In vitro experiments have shown that twice daily exposure of S. mutans to various fluoride salts has shown that only SnF2 significantly alters this organisms growth and metabolism. The antibacterial effect of SnF2 was associated with an uptake of tin into the bacteria. Fluoride salts of sodium, lead, zinc, and copper had little effect in the test system. The pH of the various fluoride salts generally had no effect on the test compound activity except for the noted inactivation of SnF2 at elevated pH's. Since SnF4 also did not affect the growth of metabolism of S. mutans, a unique property of SnF2, possibly its reactivity in an aqueous environment, may be responsible for its antibacterial properties. Stannous fluoride was compared to NaF (5 ppm F-) in the drinking water of hamsters to test whether SnF2 had greater caries inhibitory effects due to its potential antibacterial effects. The number of enamel and dentinal carious lesions in both the NaF and SnF2 group was significantly different from t [abstract truncated]

NTIS/AD-A182 108/1

475p

1987. Migration of Hazardous Substances through Soil. Part 3. Flue-Gas Desulfurization and Fly-Ash Wastes.

Authors:
Houle MJ
Long DE
Weatherhead DC
Bell RE
Ricks GK

Army Dugway Proving Ground, UT.

The Flue-Gas Desulfurization (FGD) wastes contained high concentrations of boron and fluoride and moderate amounts of arsenic, chromium, copper, lead, nickel and zinc. The beryllium and cadmium were low and mercury and selenium were very low or not detected. The fly-ash (FA) wastes contain substantial concentrations of boron, chromium, copper, fluoride, lead, nickel, and zinc. The cadmium content was low and beryllium was found in low to moderate concentrations. Mercury was not detected in the FA wastes. Boron and fluoride were found in high concentrations on the FGD supernatant liquor. Except for lead which was present in low concentrations, the other elements of interest were found in very low concentrations or were not detected. Other elements, such as calcium, potassium, and sodium were found in very high concentrations in the supernatant liquor. The magnesium concentration was low (compared to the other alkaline metals and earths) in most of the FGD waste samples. It was concluded that thes [abstract truncated]

NTIS/DE88752846

29p

1987. Some Observations of Effects from Polycyclic Aromatic Hydrocarbons (PAH) and Fluoride in Norwegian Marine Recipients of Aluminium Smelter Waste.

Author: Knutzen J

Norsk Inst. for Vannforskning, Oslo.

Observations in Norwegian marine recipients of aluminium smelter waste have only shown marked ecological effects in the near zone (< 1 km) of scrubber effluents or in the vicinity of deposits rich in PAH and fluoride. However, 1-3 orders of magnitude excess concentrations of PAH in mussels, snails and seaweeds have been observed at distances more than 20 km from the sources, thus imposing restrictions on aquaculture in a considerable fjord area. Fluoride concentrations about 5 times the normal level have been observed in seaweeds exposed to less than the double natural fluoride content of water. No significant contamination was recorded in limpets. 10 drawings, 4 tables, 31 references. (ERA citation 13:037817)

NTIS/PB88-198486

19p

1987. Fletton Brickworks Ambient Air Fluoride Study: Technical Assessment,

Author: Irwin JG

Warren Spring Lab., Stevenage (England).

A two-year study conducted by Aston University has produced a valuable data set of daily airborne fluoride concentrations in the surroundings of the Bedfordshire brickfields. The sampling methodology was subjected to a number of independent checks to ensure the quality of the data. Airborne fluoride concentrations in the Marston Vale have been mapped and the relationships with brick production, meteorology and fluoride concentration in herbage examined. There is evidence of a reduction in concentrations in recent years. Concentrations during the study met air quality standards adopted by countries within the European Community on both daily and longer time scales. (Copyright (c) Crown Copyright 1987.)

NTIS/PB89-177786

North American Continent sales only.

32p

1987. NIWR (National Institute for Water Research) Interlaboratory Comparison Studies Nos 83-87/B: Conclusions.

Author: Smith R

National Inst. for Water Research, Pretoria (South Africa).

The third of the National Institute for Water Research's (NIWR) series of interlaboratory comparison studies involving southern African laboratories engaged in water and waste-water analysis has been completed. The program consisted of 11 major studies, involving the analysis of drinking, waste and synthetic waters, as well as a river sediment and a sewage sludge, for a total of 48 different determinants. The major studies determined the following: (1) trace metals in river sediment; (2) inorganic chemical contaminants and nutrients in sewage sludge; (3) volatile halogenated hydrocarbons in water; (4) major cations and anions; (5) nutrients; (6) physical properties; (7) organic parameters; (8) trace metals; (9) cyanide, bromide, fluoride, boron and silica; (10) soap, oil and grease; and (11) various anions by ion chromatography. Two follow-up studies, involving the analysis of synthetic and waste water for (a) calcium, magnesium, and total hardness by EDTA titration, and (b) phenols were also pe [abstract truncated]

NTIS/PB89-177794

North American Continent sales only.

52p

1987. NIWR (National Institute for Water Research) Interlaboratory Comparison Study No. 87: Determination of Soap, Oil and Grease and NIWR Interlaboratory Comparison Study No. 87/B: Determination of Various Anions by Ion Chromatography. Evaluation of Results.

Authors:
Smith R
Paxton AV

National Inst. for Water Research, Pretoria (South Africa).

Studies 87 and 87/B formed part of the National Institute for Water Research's (NIWR) series of interlaboratory comparison studies involving southern African laboratories engaged in water and waste-water analysis, and are concerned with (a) the analysis of two wastewater samples for soap, oil and grease, and (b) the analysis, by means of ion chromatography, of two synthetic water, two tap water and two secondary sewage effluent samples for chloride, fluoride, bromide, sulfate, phosphate, nitrate and nitrite. Results from study no. 87/A highlighted the difficulty in obtaining adequately reliable results, using gravimetric methods, on samples with concentrations of soap, oil and grease around the maximum level of 2.5 mg/l of the General Standard of the Department of Water Affairs Regional Standard for Industrial Effluents. Consideration of the infrared technique for the determination of this parameter is recommended. Results from study no. 87/B showed ion chromatography to be acceptable for the de [abstract truncated]

NTIS/DE87010911

Paper copy only, copy does not permit microfiche production.

65p

1987. Investigation Report: Toxic Gas Release from the beta-gamma Incinerator at the Savannah River Plant on December 9, 1986.

Department of Energy, Aiken, SC. Savannah River Operations Office.

On December 9, 1986, a scheduled functional test of the Halon fire suppression system in the Feed Lag Storage Area (FLA) of the BGI facility was initiated by manually activating the Halon system. Interlocks that shutdown ventilation in the FLA operated as designed, and the 756-lb charge of Halon 1301 was released into the FLA as intended. Normal building air flow designed to minimize spread of contamination, plus a momentary increase in pressure in the FLA resulting from the discharge of Halon, caused an estimated 450 lb of Halon to enter the adjacent process room through a number of small openings in the sheetmetal separating wall. About 240 lb of the Halon was drawn into the incinerator where it thermally decomposed into hydrogen fluoride and bromine. These gases were discharged through the incinerator stack. About 10:20 a.m., some employees, working approximately 1500 ft downwind, began to experience eye and respiratory irritation. An orange-yellow plume was observed to be coming from the BGI [abstract truncated]

NTIS/DE87009465

Portions of this document are illegible in microfiche products.

Original copy available until stock is exhausted.

124p


1987.
Groundwater Chemistry at Yucca Mountain, Nevada, and Vicinity.

Author: Kerrisk JF

Los Alamos National Lab., NM.

The chemistry of groundwater at Yucca Mountain and vicinity has been reviewed and compared with the chemistry of water from the Nevada Test Site and surrounding areas such as the Amargosa Desert and Oasis Valley. Sodium is the primary cation and carbonate is the primary anion in water from the saturated zone of the tuffaceous aquifer at Yucca Mountain. Other major cations present are calcium, potassium, and magnesium; other major anions are sulfate and chloride, with lesser quantities of fluoride and nitrate. Aqueous silica is also present. The primary purpose of this review was to survey water-composition data and look for relations among the compositional variables that could provide insight into the processes that control the composition and would ultimately affect radionuclide transport. The following conclusions were inferred from the review. Major cation concentrations are controlled by rock dissolution and mineral precipitation reactions as well as by cation exchange with existing mineral [abstract truncated]

NTIS/PB87-183596

10p

1987. Preliminary Survey Report: Control Technology for Gallium Arsenide Processing at Microwave Semiconductor Corporation, Somerset, New Jersey,

Authors:
Lenihan KL
Sheehy JW

National Inst. for Occupational Safety and Health, Cincinnati, OH. Engineering Control Technology Branch.

The technology available to control hazardous substances in gallium-arsenide (1303000) applications is reviewed and evaluated in light of findings from a visit to the Microwave Semiconductor Corporation (SIC-3674) in Somerset, New Jersey. The facility has 500 employees, 64 in the gallium-arsenide technical staff. Direct ion implantation or epitaxial growth, photolithography, plasma etching, and backside wafer processing are used at the facility to fabricate a gallium-arsenide wafer. Hazards exist primarily in the numerous solvents, acids, and gases employed in wafer production. These include chlorobenzene (108907), methanol (67561), methyl-ethyl-ketone (78933), methyl-isobutyl-ketone (108101), ammonia (7664417), and silane (7803625). The use of arsine (7784421) gas will soon begin at the facility, which will also be hazardous to employees due to its extremely toxic properties. An environmental engineer tests for 70 hazardous chemicals in the work area, including hydrogen-fluoride (7664-39-3), cyan [abstract truncated]

NTIS/PB87-232948

28p

1987. Health Hazard Evaluation Report HETA 84-488-1793, J. R. Simplot Company, Pocatello, Idaho,

Authors:
Apol AG
Singal M

National Inst. for Occupational Safety and Health, Cincinnati, OH. Hazard Evaluations and Technical Assistance Branch.

In response to a request from the Oil, Chemical and Atomic Workers International Union, a health hazard evaluation was conducted at the J. R. Simplot Company (SIC-2874), Pocatello, Idaho, concerning exposures to acid mists, ammonia (7664417), fluorides, nitrogen-dioxide (10102440) (NO2), free silica (7631869), and sulfur-dioxide (7446095) (SO2). A medical and occupational history questionnaire completed by 74 men indicated that 30 percent had eye or upper respiratory complaints at least 1 to 2 days/week, and 17 percent had such complaints on most days. No relationship was found between chronic cough, chronic bronchitis or shortness of breath and length of employment. Some samples for ammonia, hydrogen-fluoride (7664-39-3), phosphoric-acid (7664382), sulfuric-acid (7664939), and SO2 exceeded the respective NIOSH recommended exposure limits (REL). The REL for free silica was also exceeded, but exposed workers wore respirators. The authors conclude that workers are overexposed to ammonia, hydrogen-fl [abstract truncated]

NTIS/PB88-185244

6p

Pub. in Jnl. of American Water Works Association v79 n10 p81-84 Oct 87.

1987. Controlling Arsenic, Fluoride, and Uranium by Point-of-Use Treatment.

Authors:
Fox KR
Sorg TJ

Environmental Protection Agency, Cincinnati, OH. Water Engineering Research Lab.

Arsenic and other inorganic contaminants are found in the water supplies of many small communities. One possible solution for the problem of inorganic contaminants is point-of-use treatment, which can be used by individual homes or small communities. Ion exchange, activated alumina, and reverse osmosis point-of-use treatment units have been evaluated by the U.S. Environmental Protection Agency, and each system was found to be effective under certain operating conditions. Data from various field projects are presented, along with laboratory data on the removal of specific contaminants. Journal article,

NTIS/PB89-120133

12p

1986. Comparative Toxicity of Six Test Chemicals to Lettuce Using Two Root Elongation Test Methods (Journal Version).

Authors:
Ratsch HC
Johndro D

Corvallis Environmental Research Lab., OR.

Lettuce (Lactuca sativa L., cv buttercrunch) was used to evaluate and compare the results from two different root elongation phytotoxicity test methods with the same six test substances. Seeds were either germinated in the dark on an inclined filter paper substrate with one end immersed in test solution or germinated in 0.1 strength nutrient solution with a 16 hr light period in a glass bulb mixed and aerated with compressed air. Sodium fluoride, monosodium methanearsonate and monuron reduced lettuce root length at similar concentrations for both methods; with cadmium chloride and 2,4-D root inhibition occurred at concentrations approximately one order of magnitude smaller in the solution culture method than in the substrate method. Two orders of magnitude difference were observed between the two methods for silver nitrate. The results indicate that the solution method is at least as sensitive for all the chemicals tested and much more sensitive for some. Journal article, Pub. in Environmental [abstract truncated]

NTIS/DE88705128

U.S. Sales Only.

167p

1986. Comparison of the Rationale Used in Setting Occupational Exposure Standards for Ionizing Radiation and Hazardous Chemical Substances.

Author: Halton DM

Atomic Energy Control Board, Ottawa (Ontario).

Ten chemicals which create significant occupational hazard are reviewed. They are toluene diisocyanate, hydrogen fluoride, n-hexane, carbon disulphide, cadmium, inorganic mercury, cobalt, nitroglycerol, silica and vinyl chloride. Each is discussed under the headings of physiological intake and elimination in humans, characteristics of acute and chronic toxicity, sites of occupational exposure and rationale for limits of such exposure. Since radioactive substances yield ionizing radiation as the common hazard the treatment of the current permissible levels of exposure is somewhat simpler. Having set out industrial standards for exposure to hazardous substances and radionuclides, a detailed comparison is made. Exposure limits to ioninzing radiation are sufficiently low to remove the appearance of directly related injury. It is expected however that low level exposure may have a stochastic effect, that is, there is the possibility of a slightly increased incidence of neoplasms in a large exposed po [abstract truncated]

NTIS/PB87-102547

110p

1986. Effect of Severe Dental Fluorosis on the Oral Health of Adults.

Authors:
Eklund SA
Burt BA
Ismail AI
Calderone JJ

Michigan Univ., Ann Arbor. School of Public Health.
New Mexico Health and Environment Dept., Santa Fe.

The purpose of the study was to measure the prevalence and distribution of a series of oral health measures in lifelong adult residents of two New Mexico communities. One community, Deming, had a natural fluoride concentration of approximately 0.7 mg/l in its drinking water, optimum for its climate. The other community, Lordsburg, was naturally fluoridated at approximately 3.5 mg/l, five times optimum. Dental examinations were conducted on 187 adults in Lordsburg and 189 adults in Deming. The results of the investigation, while confirming the cosmetic effects of fluorosis, do not give any obvious support to the need for the fluoride levels in Lordsburg to be reduced. While on some of the aspects measured one community or the other is slightly better off, it is fair to say that none of the differences are of great consequence. The slight advantages with respect to root caries and coronal caries that the residents of Lordsburg enjoy are not enough to recommend higher levels of fluoride. On the oth [abstract truncated]

NTIS/PB87-178380

45p

1986. Marion County Solid Waste-to-Energy Facility Boilers 1 and 2. Air Emissions Source Test Report.

Ogden Projects, Inc., Emeryville, CA.

Sponsored by Oregon State Dept. of Environmental Quality, Salem, and Ogden Martin Systems of Marion, Inc., Brooks, OR.

The report presents the results of source testing conducted at the Ogden Martin Systems of Marion, Inc., facility in Marion County, Oregon. The 550 tons-per-day facility has two municipal solid waste-fired boilers, each equipped with dry acid gas scrubbing equipment and a baghouse. Source testing was conducted at the stack for nitrogen oxides, sulfur dioxide, carbon monoxide, total suspended particulate, volatile organic compounds, lead, beryllium, mercury, chlorides, fluoride, and tetra through octa-chlorodibenzo-o-dixons and -chlorodibenzofurans. Executive summary.

NTIS/DE87004968

5p

1986. Action of Tumor Initiators and Promoters in the Syrian Hamster Embryo Cell Transformation Assay.

Authors:
Jones CA
Huberman E

Argonne National Lab., IL.

Supporting Agency: Department of Energy, Washington, DC.

The Syrian hamster embryo (SHE) cell transformation assay is unique among the rodent fibroblast transformation systems in that it uses normal, diploid cells. Alteration in the control of growth in carcinogen-treated cultures is used to indicate the onset of neoplastic development. An evaluation of the SHE assay for screening carcinogens is reported. Using coded chemicals, the degree of intra- and interlaboratory reproducibility with the system was evaluated. Overall, there was a good qualitative correlation between the carcinogenicity of the chemicals and their ability to induce morphological cell transformation. Unfortunately, the low level of response and lack of good dose-response relationships with certain chemical are still major constraints to the use of this system in routine testing. Further consideration needs to be given to developing procedures that select for, or amplify, expression of the transformed phenotype. 9 refs., 2 figs., 1 tab. (ERA citation 12:023689) Annual DOE contractor
Keywords:
Benzopyrene
Cholecalciferol
Pyrene
Sodium Fluorides

NTIS/DE86011327,

Portions of this document are illegible in microfiche products.

21p

1986. Fluoride Levels in Vegetation in the Vicinity of the Portsmouth Gaseous Diffusion Plant. Final Report.

Author: Jackson DR

Battelle Columbus Labs., OH.

Supporting Agency: Goodyear Atomic Corp., Piketon, OH
Department of Energy, Washington, DC.

Battelle initiated a survey of vegetation samples at new and established sites in the vicinity of the Portsmouth Gaseous Diffision Plant. Forty-nine vegetation samples were collected and analyzed for fluoride. Three samples from inside the plant boundaries contained fluoride in concentrations great enough to be of concern to grazing livestock (>40 ppm). All other samples were below the action level. Fluoride concentrations in vegetation reported by Battelle were somewhat greater than identical samples analyzed by GAT. This differences may be accounted for by the fact that GAT rinsed their samples prior to the analysis for fluoride while Battelle did not. Battelles' samples were not washed because fluoride containing particulates on the surface of vegetation can be readily ingested by livestock and may contribute to the total amount of fluoride absorbed by the livestock. Results of the vegetational survey were not correlated with the deposition pattern modeled by Battelle. Apparently, levels o [abstract truncated]

NTIS/PB87-166195

86p

1986. Risk Assessment of Exposure to Radium and Fluoride in Illinois Public Water Supplies,

Author: Hallenbeck WH

Illinois Univ. at Chicago Circle.

In June of 1985, the Illinois Environmental Protection Agency petitioned the Illinois Pollution Control Board to suspend the restricted status of certain communities until January 1, 1989. The effect of this proposal would be to raise the Maximum Allowable Concentrations (MAC) of fluoride from 1.8-2.0 mg/1 to 4 mg/1, and combined radium from 5 to 20 pCi/1. The overall objective of the report was to assess the potential health impacts of these proposed changes in MACs. Pertinent literature and IPCB testimony were evaluated, health impact models were constructed, and individual risks and/or expected cases were calculated for each affected community. There are 107 communities (680,912 people) in Illinois whose water supplies exceed the present Illinois standard of 5 pCi/1 of combined radium. There are 46 communities (53,840 people) in Illinois whose water supplies exceed the present Illinois standard of 1.8 to 2.0 mg/1 of fluoride. Sponsored by Illinois Dept. of Energy and Natural Resources, Sprin [abstract truncated]

NTIS/PB86-247483

82p

Also available from Supt. of Docs as SN003-003-02750-2.

1986. Methods and Procedures Used at the National Bureau of Standards to Prepare, Analyze and Certify SRM (Standard Reference Material) 2694, Simulated Rainwater, and Recommendations for Use.

Author: Koch WF

National Bureau of Standards (NML), Gaithersburg, MD. Center for Analytical Chemistry.

The report describes the development, preparation, analysis and certification of Standard Reference Material, SRM 2694, Simulated Rain-water, intended to aid in the analysis of acidic rainfall. Details of the formulation and preparation of the two levels of solutions (2694-I and 2694-II) are given, as well as those of the precursor to the SRM, namely Research Material, RM 8409, Simulated Rainwater. The analytical techniques used to measure the twelve components in the solutions are described in detail. The data used in the statistical evaluation of the results are summarized and the recommended values for pH, specific conductance, acidity, fluoride, chloride, nitrate, sulfate, sodium, potassium, ammonium, calcium, and magnesium are tabulated. The instability of ammonium ion in acidic solutions is discussed. Recommendations for the use of SRM 2694, particularly with regard to the measurement of pH, are given. Final rept.

NTIS/DE86012032

6p

1986. Prediction of Critical Grout Parameters: Critical Flow Rate.

Authors:
Tallent OK
McDaniel EW
Godsey TT
Dodson KE

Oak Ridge National Lab., TN.

Supporting Agency: Department of Energy, Washington, DC.

Waste disposal is rapidly becoming one of the most important technological endeavors of our time and fixation of waste in cement-based materials is an important part of the endeavor. Investigations of given wastes are usually individually conducted and reported. In this study, data obtained from investigation of critical flow rates for three distinctly different wastes are correlated with apparent viscosity data via a single empirical equation. Critical flow rate, which is an important variable in waste grout work, is defined as the flow rate at which a grout must be pumped through a reference pipe to obtain turbulent flow. It is important that the grout flow be turbulent since laminar flow allows caking on pipe walls and causes eventual plugging. The three wastes used in this study can be characterized as containing: (1) high nitrate, carbonate, and sulfate; (2) high phosphate; and (3) high fluoride, ammonium, and suspended solids waste. The measurements of apparent viscosity (grouts are non-Ne

NTIS/NUREG-1189-V2

425p

1986. Assessment of the Public Health Impact from the Accidental Release of UF6 at the Sequoyah Fuels Corporation Facility at Gore, Oklahoma, Docket No. 40-8027, License No. SUB-1010. Appendices.

Nuclear Regulatory Commission, Washington, DC.

Following the accidental release of UF6 from the Sequoyah Fuels Facility on January 4, 1986, an Ad Hoc Interagency Public Health Assessment Task Force was established. The Task Force consists of technical staff members from various agencies who have prepared this assessment of the public health impact associated with the accidental release. The assessment is based on data from the accident available as of February 14, 1986, and describes the chemical and radiological effects from the intake of uranium and fluoride. Volume 2 of the report consists of Appendices which provide more detailed information used in the assessment.

NTIS/PB86-194420

112p

1986. Investigation of the Formation of a Portland Cement Plant Detached Plume,

Authors:
Cheney JL
Knapp KT

Environmental Protection Agency, Research Triangle Park, NC. Atmospheric Sciences Research Lab.

A gaseous and particulate source emissions sampling program has been conducted at a Portland Cement production plant in Rapid City South Dakota. The study was conducted to determine the cause of the formation of an opaque detached plume from the plants' dry process kiln. The instack opacity of the emissions was less than 10 percent while the opacity of the plume five to ten stack diameters from the mouth of the stack was in excess of 40 percent, thus giving an appearance of a detached plume. The sampling and analysis program included particulate emissions measurements, particle sizing and composition, and measurements of gaseous and particle ammonia, chloride, fluoride, and sulfur dioxide. Extensive process materials sampling and analysis were also conducted. Based on the resulting data one conclusion is that the opaque detached plume is the result of ammonium chloride particles formed by the reaction of gaseous ammonia and hydrochloric acid. It was also found that the ammonia in the cement plan [abstract truncated]

NTIS/02010171

6p

1986. Thermally stimulated depolarization currents in the natural fluorite.

Author: Valerio MEG

Sao Paulo Univ., SP (Brazil). Inst. de Fisica.

THESIS.
Portuguese.
The present work deals with natural calcium fluoride from Criciuma, Santa Catarina. Thermally Stimulated Depolarization Currents (TSDC) can be used to determine the properties of dipole defects present in this crystal. The TSDC spectrum of this material shows three bands in the temperature range of 80 to 450 K. The first one, at 130 K, is due the dipoles formed by a trivalent impurity and an interstitial fluorine ion in the next nearest position of an impurity ion (nn R(sub s)(sup 3+) -F(sub i)(sup -)). The second one, at 102 k, is due to the presence of small aggregates of dipoles (like a dimer). The last band, at 360 k is due to the formation of Large Clusters. The continuous distribution model gave the best fit for these bands with mean activation energies of 0.41 eV, 0.595 eV and 1.02 eV for the first, second and third band respectively. Thermal treatments can modify the number of dipoles, dimers and clusters present in the crystal. The variation in the areas under each band can be used to measure this effect. In this work we used thermal treatments between 15 minutes and 10 hours and temperatures between 200 deg C and 500 deg C. For thermal treatments at 300 deg C, the dipoles and dimers are created and the clusters are destroyed as the time of thermal treatment increases. At 400 deg C the clusters are created and the dipoles and dimers and 350 deg C for the clusters. (author) 60 refs., 41 figs., 1 tab.

NTIS/NUREG-1179-V1

145p

1986. Rupture of Model 48Y UF sub 6 Cylinder and Release of Uranium Hexafluoride, Sequoyah Fuels Facility, Gore, Oklahoma, January 4, 1986,

Authors:
Smith RD
Cain CL
Chappell R

Nuclear Regulatory Commission, Washington, DC.

At 11:30 a.m. on January 4, 1986, a Model 48Y UF6 cylinder filled with uranium hexafluoride (UF6) ruptured while it was being heated in a steam chest at the Sequoyah Fuels Conversion Facility near Gore, Oklahoma. One worker died because he inhaled hydrogen fluoride fumes, a reaction product of UF6 and airborne moisture. Several other workers were injured by the fumes, but none seriously. Much of the facility complex and some offsite areas to the south were contaminated with hydrogen fluoride and a second reaction product, uranyl fluoride. The interval of release was approximately 40 minutes. The cylinder, which had been overfilled, ruptured while it was being heated because of the expansion of UF6 as it changed from the solid to the liquid phase. The maximum safe capacity for the cylinder is 27,560 pounds of product. Evidence indicates that it was filled with an amount exceeding this limit.

NTIS/PB87-231882

35p

1986. Near Field Atmospheric Dispersions of Effluents Adjacent to an Aluminium Refinery.

Authors:
Barnes RD
Watkins RD

Sydney Univ. (Australia). School of Civil and Mining Engineering.

The prediction of dispersion, especially in nearer field areas, of fluoride effluents from a mixture of low level line sources and medium level stack sources does not seem readily amenable to mathematical modeling, and wind tunnel model testing is likely to be a more effective method. The paper describes the procedures and results of on-site measurements at Tomago Refinery near Newcastle, N.S.W., which will provide data for checking the efficacy of wind tunnel modeling. Research rept.,

NTIS/DE86008702

Portions of this document are illegible in microfiche products

17p

1986. Evaluation of the Validity and Statistical Variability of Lithium and Fluoride Distribution Coefficient Values in a Complex Geochemical System.

Authors:
Pavlik HF
Runnells DD

Colorado Univ. at Boulder. Dept. of Geological Sciences.

Predictive modeling of solute transport requires accurate measurement or estimation of geochemical adsorption and ion exchange parameters for a given rock-fluid system. One such parameter is the distribution coefficient (Kd) used to predict the rate of movement of dissolved contaminant through soils and aquifers. The Kd describes the partitioning of a dissolved species between a solid phase and the aqueous solution in equilibrium with the solid phase. This research presents a statistical evaluation of the validity of the distribution coefficient to describe adsorption of lithium and fluoride in a complex, natural rock-fluid system. The general goal of the research was to generate Kd parameters appropriate for simulating contaminant migration from oil shale waste disposal sites planned for the Piceance Creek Basin of western Colorado. Specific objectives were to: (1) test the key assumptions that control valid application of the Kd in any rock-fluid system. Included among these are the assumption [abstract truncated]

NTIS/PB87-131629

 

166p

1986. Primary Aluminum: Statistical Analysis of Potline Fluoride Emissions and Alternate Sampling Frequency.

Environmental Protection Agency, Research Triangle Park, NC. Office of Air Quality Planning and Standards.

Statistical analyses were performed on 4 years of fluoride emissions data from a primary aluminum reduction plant. These analyses were used to develop formulae and procedures for use by regulatory agencies in determining alternate sampling frequencies for secondary (roof monitor) emissions testing on a case-by-case basis. Monitoring procedures for ensuring compliance even with a reduced test frequency are also addressed. Final rept.

NTIS/AD-A168 314/3

460p

1986. Investigation of Source of Irritant Gas Produced by PATRIOT Missile System Air Conditioners.

Authors:
Lawrence LG
Perkins GW
Tanner JD

VSE Corp., Alexandria, VA.

Reported illnesses of persons working in PATRIOT Missile System equipment shelters were investigated and found to have been caused by exposure to Hydrolyzable Fluoride (HF). PATRIOT mil spec 18,000 BTU Split-Package Air Conditioners (ACs) produced HF when their heater rod Teflon grommets outgassed upon being subjected to temperatures exceeding 400 F. A PATRIOT Support Project Office retrofit program for series '80 and '81 ACs and engineering changes to series '82 and later units eliminated the TFE grommets and solved the HF exposure problem. Keywords: Ground support systems; Air conditioning equipment; Tetrafluoroethylene resins; Hydrolyzable fluoride; Plastic material outgassing. Final rept. 5 Apr 82-9 Dec 83, [abstract truncated]

NTIS/PB93-199297

156p

1986. Standards of Performance for New Stationary Sources. Volume 1. Introduction, Summary and Standards: A Compilation as of December 31, 1985.

Author: Zieleniewski J

PEI Associates, Inc., Cincinnati, OH.

Sponsored by Environmental Protection Agency, Research Triangle Park, NC. Office of Air Quality Planning and Standards.

The document provides the compliance standards for new stationary air pollution sources. Acceptance levels are given for sulfur dioxide, carbon dioxide, carbon monoxide, nitrogen oxide, sulfuric acid, hydrogen sulfide, fluoride, and other exhaust emissions. Standards of performance given include those for steam generating units, steel plants, pulp mills, glass manufacturing, grain elevators, surface coating of metal furniture, gas turbines, synthetic fiber production, dry cleaners, onshore natural gas processing, Nonmetallic mineral processing, and fiberglass insulation manufacturing. See also PB80-194913

NTIS/DE87752052

U.S. Sales Only.

Portions of this document are illegible in microfiche products.

26p

1986. Emissions from a Fluidized Bed Boiler.

Authors:
Aamand LE
Johansson S
Karlsson M
Leckner B

Statens Energiverk, Stockholm (Sweden).

The present study is undertaken to provide information on the gaseous emissions from a commercial size stationary fluidized bed boiler (a boiler with a fluidized bed run with little or no recirculation of bed material from the flue gases). An additional purpose of the study is to use the emission data for a comparison with the emissions from a boiler with a circulating fluidized bed. The two boilers are run with the same coal and the same bed materials (sand and limestone). The present report contains the results from the stationary bed boiler. The emissions considered are those of sulphur and nitrogen oxides. In addition, sampling of chloride, fluoride and mercury has been made at single occasions. (ERA citation 12:031686)

NTIS/DE90617556

U.S. Sales Only.

107p

1986. (Somatic mutations in Tradescantia as a model system for studying the effects of the environmental agents).

Author: Cebulska-Wasilewska A

Institute of Nuclear Physics, Krakow (Poland).

The application of the plant model system for studying the biological effects of ionizing radiation and chemical mutagens is presented. The model system is based on the somatic mutation frequency in stamen hair cells of Tradescantia clones heterosygous for flower color. The interaction of chemical mutagens with radiation in the induction of somatic mutations was investigated. The results demonstrate the synergistic interaction between radiation and chemical mutagens like ethyl methanesulfonate and di-bromoethane. The synergistic effect is clearly manifested after combined treatment with radiation and chemicals. In the low dose region the effect depends on the radiation dose and chemical exposure. Other results show the influence of the fluoride treatment on the radiation effect. The fluoride treatment is likely to alter the DNA double strand breaks repair processes. Additionally the usefulness of the model system for studying the mutagenic effectiveness of the pollution in the ambient air is pre [abstract truncated]

NTIS/NUREG-1189-V1

100p

1986. Assessment of the Public Health Impact from the Accidental Release of UF6 at the Sequoyah Fuels Corporation Facility at Gore, Oklahoma, Docket No. 40-8027, License No. SUB-1010. Main Report.

Nuclear Regulatory Commission, Washington, DC.

Following the accidental release of UF6 from the Sequoyah Fuels Facility on January 4, 1986, an Ad Hoc Interagency Public Health Assessment Task Force was established. The Task Force consists of technical staff members from various agencies who have prepared this assessment of the public health impact associated with the accidental release. The assessment is based on data from the accident available as of February 14, 1986, and describes the chemical and radiological effects from the intake of uranium and fluoride. Volume 1 of the report describes the effects from the intake of uranium and fluoride and summaries the findings and recommendations of the Task Force. See also NUREG-1189-V2.

NTIS/DE87014012

Portions of this document are illegible in microfiche products. Original copy available until stock is exhausted.

40p

1986. Inorganic Solute Profiles of Waters Related to Rio Blanco Oil Shale Project Retort 1.

Authors:
Poulson RE
Borg HM

University of Wyoming Research Corp., Laramie. Western Research Inst.

Water samples were taken from the Rio Blanco oil shale project retort 1 site approximately three- and one-half years after the shutdown of the oil recovery phase. Intermittent flooding and pumpdown of the retort occurred in the interval between shutdown and sampling for this study. Waters from within the retort and from downgradient and offsite locations were compared using a battery of analyses for inorganic and general water quality parameters. Inorganic solute species were selected as potential key indicator species if the particular species concentration inside the retort was greater than that outside the retort. Six inorganic parameters were found to qualify as potential key indicators for retort water migration from the site: potassium, lithium, ammonia, fluoride, thiosulfate, and boron. Except for ammonia, these indicators differ from those selected by other researchers at other modified in situ retorting sites. Ion chromatographic techniques were shown to be applicable for five of the si [abstract truncated]

NTIS/PB86-235652

37p

1986. North Carolina Water Quality Standards Documentation: Toxicity of Fluoride to Freshwater Biota.

North Carolina Dept. of Natural Resources and Community Development, Raleigh. Div. of Environmental Management.

Keywords:
Fluorides
Toxicity
Fresh water biology
 
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