FLUORIDE ACTION NETWORK PESTICIDE PROJECT

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For original MSDS see http://www.horizononline.com/MSDS_Sheets/529.txt

RESOURCE TM HERBICIDE

This Material Safety Data Sheet (MSDS) serves different purposes than and DOES NOT REPLACE OR MODIFY THE EPA-APPROVED PRODUCT LABELING (attached to and accompanying the product container). This MSDS provides important health, safety, and environmental information for employers, employees, emergency responders, and others handling large quantities of the product in activities generally other than product use, while the labeling provides that information specifically for product use in the ordinary course. Use, storage, and disposal of pesticide products is regulated by the EPA under the authority of the Federal Insecticide, Fungicide, and Rodenticide Act (FIFRA) through the product labeling. All necessary and appropriate precautionary, use, storage, and disposal information is set forth on that labeling. It is a violation of Federal law to use a pesticide product in any manner not prescribed on the EPA-approved label.

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SECTION 1: CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
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PRODUCT NAME: RESOURCE TM Herbicide
PRODUCT NUMBER(S): 68110
EPA REGISTRATION NUMBER: 59639-82
SYNONYM(S): V-23031 Herbicide S-23031 Herbicide
VALENT USA CORPORATION
P.O. Box 8025
1333 N. California Blvd., Suite 600
Walnut Creek, CA 94596-8025
EMERGENCY TELEPHONE NUMBERS
HEALTH EMERGENCY OR SPILL (24 hr):(800) 892-0099TRANSPORTATION (24 hr):
CHEMTREC
(800) 424-9300 or (202) 483-7616PRODUCT INFORMATION:
AGRICULTURAL PRODUCTS:(800) 6VALENTPROFESSIONAL PRODUCTS:(800) 89VALENT

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SECTION 2: COMPOSITION/INFORMATION ON INGREDIENTS
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SECTION 3: HAZARDS IDENTIFICATION
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**************************** EMERGENCY OVERVIEW****************************
WARNING:
--CAUSES EYE IRRITATION
--HARMFUL IF SWALLOWED OR ABSORBED THROUGH THE SKIN
--DO NOT GET ON SKIN, IN EYES, OR ON CLOTHING
--KEEP OUT OF REACH OF CHILDREN
***************************************************************************

POTENTIAL HEALTH EFFECTS Acute Toxicity (Primary Routes of Exposure)

Signs and Symptoms of Systemic Effects: Signs of toxicity in test animals at lethal or near-lethal acute doses included salivation, changes in respiratory rate, decreased activity, lacrimation, abnormal gait, and body tremors.

Eye: This product has been shown to cause prolonged or significant eye irritation. The degree of injury will depend on the amount and duration of contact and the speed and thoroughness of the first aid treatment. The expected adverse health effects resulting from an exposure may include redness, swelling, and pain which could last for an extended period of time.

Skin: This product has been shown to cause prolonged and/or significant skin irritation. The degree of injury will depend on the amount and duration of the contact and the speed and thoroughness of the first aid treatment. The expected adverse health effects resulting from an exposure may include redness, swelling, and pain for an extended period of time. This product is not expected to cause allergic skin reactions. This product has been shown to be slightly toxic when absorbed through the skin. The degree of injury will depend on the amount of material absorbed and the speed and thoroughness of the first aid treatment. The expected adverse systemic health effects resulting from an exposure are described above.

Ingestion: This product has been shown to be slightly toxic when ingested. The degree of injury will depend on the amount of material ingested and the speed and thoroughness of the first aid treatment. The expected adverse systemic health effects resulting from an exposure are described above.

Inhalation: Exposure to very high concentrations may result in respiratory irritation. Signs and symptoms may include nasal discharge, sore throat, coughing, and difficulty in breathing. This product has been shown to be minimally toxic when inhaled. The degree of injury will depend on the amount of material inhaled and the speed and thoroughness of the first aid treatment. The expected adverse systemic health effects are described above.

Chronic Toxicity (Including Cancer): Studies with Flumiclorac Pentyl Technical indicate that repeated high exposures produced changes in liver, kidney, and red blood cells but did not produce cancer in test animals.

Teratology (Birth Defects) Information: No developmental toxicity was produced in animals exposed to Flumiclorac Pentyl Technical, even at doses that were toxic to the pregnant animal.

Reproduction Information: Flumiclorac Pentyl Technical did not produce reproductive toxicity in animal studies.

Potentially Aggravated Condition: Individuals with preexisting diseases of the liver, kidney, or red blood cells may have increased susceptibility to the toxicity of excessive exposures.

For complete discussion of the toxicology data from which this evaluation was made, refer to Section 11.

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SECTION 4: FIRST AID MEASURES
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EMERGENCY NUMBER (800) 892-0099
EYES: Flush eyes immediately with plenty of fresh water. Remove contact lenses if worn. No additional first aid should be necessary. However, if irritation persists, see a doctor.
SKIN: Remove contaminated clothing. Wash skin thoroughly with soap and water. See a doctor if any signs or symptoms described in this document occur. Discard contaminated non-waterproof shoes and boots. Wash contaminated clothing.
INGESTION: If swallowed, give 1 or 2 glasses of water or milk to drink and telephone for medical advice. DO NOT make person vomit unless directed to do so by medical personnel. If medical advice cannot be obtained, then take the person and product container to the nearest medical emergency treatment center or hospital.
INHALATION: If respiratory discomfort or irritation occurs, move the person to fresh air. See a doctor if discomfort or irritation continues.
NOTES TO PHYSICIAN: This material contains light hydrocarbon liquid and an aspiration hazard may exist.

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SECTION 5: FIRE FIGHTING MEASURES
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FLASH POINT: 154F (68C)
METHOD: Closed Cup
AUTOIGNITION: NDA
EXTINGUISHING MEDIA: CO2, dry chemical.
FLAMMABLE LIMITS (% by volume in air):
Lower: NDA
Upper: NDA
NFPA RATINGS: Health 1; Flammability 2; Reactivity 0; Special NDA (Least-0, Slight-1, Moderate-2, High-3, Extreme-4). These values are obtained using the guidelines or published evaluations prepared by the National Fire Protection Association, NFPA.
OTHER CONSIDERATIONS: None.
FIRE FIGHTING INSTRUCTIONS: For fires involving this material, do not enter any enclosed or confined fire space without proper protective equipment. This may include self-contained breathing apparatus to protect against the hazardous effects of normal products of combustion or oxygen deficiency. Read the entire MSDS document.
HAZARDOUS COMBUSTION PRODUCTS: Normal combustion forms carbon dioxide, water vapor and may produce oxides of nitrogen. Combustion may produce toxic compounds of chlorine & fluorine. Incomplete combustion can produce carbon monoxide.

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SECTION 6: ACCIDENTAL RELEASE MEASURES
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VALENT EMERGENCY PHONE NUMBER: (800) 892-0099
CHEMTREC EMERGENCY PHONE NUMBER: (800) 424-9300
OBSERVE PRECAUTIONS IN SECTION 8: PERSONAL PROTECTION Stop the source of the spill if safe to do so. Contain the spill to prevent further contamination of the soil, surface water, or ground water.
FOR SPILLS ON LAND:
CONTAINMENT: Avoid runoff into storm sewers and ditches which lead to waterways. Contain spilled liquids with dry sorbents.
CLEANUP: Clean up spill immediately. Absorb spill with inert material (such as dry sand or earth), then place in a chemical waste container. Wash area with soap and water. Pick up wash liquid with additional absorbent and place in a disposable container.
FOR SPILLS IN WATER:
CONTAINMENT: This material forms an emulsion in water. Stop or reduce contamination of any water. Isolate contaminated water.
CLEANUP: Remove contaminated water for removal or treatment.

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SECTION 7: HANDLING AND STORAGE
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END USER MUST READ AND OBSERVE ALL PRECAUTIONS ON PRODUCT LABEL.
Do not use or store near flame, sparks, or hot surfaces. Use only in well-ventilated area. Keep container closed. Keep pesticide in original container. Do not store or transport near food or feed. Do not put concentrate in food or drink containers. Do not dilute concentrate in food or drink containers. Store in a secure, preferably locked, cool, dry storage area away from heat, open flame, and direct sunlight.

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SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
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END USER MUST READ AND OBSERVE ALL PRECAUTIONS ON PRODUCT LABEL.
EYE PROTECTION: Do not get this material in your eyes. Eye contact can be avoided by wearing protective eyewear.
RESPIRATION/VENTILATION: This material may be a respiratory irritant and, unless ventilation is adequate, the use of approved respiratory protection is recommended.
SKIN PROTECTION: Do not get on skin or clothing. Skin contact should be minimized by wearing protective clothing including long-sleeve shirt, long pants, socks, shoes, and chemical resistant gloves (such as nitrile or butyl).

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SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
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APPEARANCE: Medium brown to dark red clear liquid.
ODOR: Aromatic odor.
MELTING POINT: NA
BOILING POINT: NA
DENSITY/BULK DENSITY/
SPECIFIC GRAVITY: 0.971 g/ml @ 20C/20C
SOLUBILITY: Emulsifiable in water.
VAPOR PRESSURE: NA
DISSOCIATION CONSTANT: NA
OCTANOL/WATER PARTITION
COEFFICIENT: NA
pH: 5.0 @ 20C
VISCOSITY: @ 25.1C: 10.6 centipoise at 30 rpm, 14.1 centipoise at 60 rpm
MISCIBILITY: NA
CORROSION CHARACTERISTICS: Not corrosive to containers for one year at ambient temperature.
EVAPORATION RATE: NDA

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SECTION 10: STABILITY AND REACTIVITY
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CHEMICAL STABILITY: Stable.
INCOMPATIBILITY: NDA
HAZARDOUS DECOMPOSITION PRODUCTS: NDA
HAZARDOUS POLYMERIZATION: Polymerization will not occur.
IMPACT EXPLODABILITY: Not explosive.
OXIDATION/REDUCTION PROPERTIES: Not reactive.

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SECTION 11: TOXICOLOGICAL INFORMATION
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ACUTE (Product Specific Information):

Eye Irritation: This product produced moderate eye irritation in rabbits which cleared within 14 days. (Toxicity Category II)

Skin Irritation: This product produced severe skin irritation in rabbits. (Toxicity Category II)

Dermal Toxicity: The dermal LD50 in rats is greater than 2 g/kg. (Toxicity Category III)

Oral Toxicity: The oral LD50 in rats is 3.2 g/kg for females and 4.1 g/kg for males. (Toxicity Category III)

Inhalation Toxicity: The 4-hour inhalation LC50 in rats is 5.51 mg/l. (Toxicity Category IV)

Skin Sensitization: This material was not a skin sensitizer in a Buehler guinea pig sensitization study. It did produce a positive sensitization response when injected intradermally in a guinea pig Maximization test. Results from the study using the Buehler method are considered more relevant to actual exposures scenarios since it uses a topical application and therefore this product is not considered a skin sensitizer.

SUBCHRONIC: Compound-related effects noted at very high dose levels of Flumiclorac Pentyl Technical in rodents and/or dogs included: increased liver and kidney weights; histological changes in the kidney and liver; slight changes in blood biochemistry parameters; decreased red blood cell count, hemoglobin, and hematocrit; and slight decreases in body weight. The NOEL in rats and mice was 1000 ppm.

CHRONIC/CARCINOGENICITY: Effects of long-term high dose exposures to Flumiclorac Pentyl Technical in rodents and/or dogs consisted primarily of increases in kidney and liver weights, slight changes in blood biochemistry, and histological changes in the liver. The lowest NOEL was 300 ppm in the mouse study. Flumiclorac Pentyl Technical was not carcinogenic in either rats or mice.

TERATOLOGY/DEVELOPMENTAL TOXICITY: No developmental toxicity was observed in rats or rabbits even at maternally toxic levels of Flumiclorac Pentyl Technical. In rabbits the maternal NOEL was 400 mg/kg/day and the developmental NOEL was 800 mg/kg/day. In rats the maternal and developmental NOELs were 1500 mg/kg/day.

REPRODUCTION: Reproductive toxicity (higher rate of F1 pup deaths on Day of lactation) as well as systemic toxicity were observed in rats at doses of 10,000 and 20,000 ppm Flumiclorac Pentyl Technical in a two-generation rat reproduction study. A repeat study for one generation did not confirm the reproductive toxicity finding. Thus, Flumiclorac Pentyl Technical is not considered a reproductive toxicant.

MUTAGENICITY: Flumiclorac Pentyl Technical was not mutagenic in most assays: gene mutation (with and without S-9 activation), unscheduled DNA synthesis, in vitro chromosomal aberration (with S-9), and in vivo mouse micronucleus. Only a weak positive response was observed in the in vitro chromosomal aberration assay in the absence of S-9 metabolic activation. Overall, Flumiclorac Pentyl Technical is not a genetic hazard.

OTHER: This product contains an inert ingredient or technical grade impurity which can cause reversible, moderate to severe eye, upper respiratory tract (e.g. mouth, nose, and throat), and skin irritation following contact with either the liquid material or high concentrations of its vapors. Long-term or repeated application of the liquid material to the skin can result in severe dermatitis with drying, redness, blistering, and edema. Long-term inhalation of its vapors by experimental animals did not produce any significant toxic effects. This material did not produce birth defects in experimental animals following exposure via ingestion, skin contact, or inhalation. No data regarding the potential of this material to cause reproductive or developmental toxicity in humans are available. This material did not produce cancer in experimental animals following inhalation exposure. No data regarding the potential of this material to cause cancer in humans are available. This material was not mutagenic in the vast majority of in vitro studies in which is was tested. This product contains a solvent that, when inhaled, can cause nasal and respiratory irritation and central nervous system effects including dizziness, weakness, fatigue, nausea, headache, and possible unconsciousness and even death. Ingestion of this chemical can cause gastrointestinal irritation, nausea, vomiting, and diarrhea. Aspiration of material into the lungs can cause chemical pneumonitis which can be fatal.

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SECTION 12: ECOLOGICAL INFORMATION
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AVIAN TOXICITY: Flumiclorac Pentyl Technical is practically nontoxic to avian species. The following results were obtained from studies with Flumiclorac Pentyl Technical.
LD50 quail: greater than 2250 mg/kg
LC50 duck: greater than 5620 ppm
LC50 mallard: greater than 5620 ppm
Quail Reproduction NOEC: 500 ppm
Duck Reproduction NOEC: 250 ppm

AQUATIC ORGANISM TOXICITY: The toxicity of Flumiclorac Pentyl Technical to freshwater fish and invertebrates ranges from slight to moderate. To saltwater/estuarine fish and invertebrates, its toxicity ranges from slight to moderate.
96-hour LC50 bluegill sunfish: 17.4 mg/l
96-hour LC50 rainbow trout: 1.1 mg/l
48-hour LC50 Daphnia magna: greater than 38.0 mg/l
96-hour LC50 sheepshead minnow: greater than 24 mg/l
96-hour EC50 eastern oyster: greater than 1.8 mg/l
96-hour LC50 mysid shrimp: 0.56 mg/l

OTHER NONTARGET ORGANISM TOXICITY: Flumiclorac Pentyl Technical is practically nontoxic to bees. The acute contact LD50 is greater than 106 ug/bee.

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SECTION 13: DISPOSAL CONSIDERATIONS
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END USERS MUST DISPOSE OF ANY UNUSED PRODUCT AS PER THE LABEL RECOMMENDATIONS.
DISPOSAL METHODS: Do not contaminate water, food, or feed by storage, disposal, or cleaning of equipment. Open dumping is prohibited. Dispose in accordance with applicable laws and regulations.

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SECTION 14: TRANSPORT INFORMATION
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D.O.T. SHIPPING NAME: Compounds, Weed Killing, Liquid, (Non-Regulated)
TECHNICAL SHIPPING NAME: Flumiclorac pentyl 10% Solution
D.O.T. HAZARD CLASS: NA
U.N./N.A. NUMBER: NA

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SECTION 15: REGULATORY INFORMATION
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REGULATIONS UNDER FIFRA: All pesticides are governed under FIFRA (Federal Insecticide, Fungicide, and Rodenticide Act). Therefore, the regulations presented below are pertinent only when handled outside of the normal use and applications of pesticides. This includes waste streams resulting from manufacturing/formulation facilities, spills, or misuse of products, and storage of large quantities of products containing hazardous or extremely hazardous substances.

OTHER U.S. FEDERAL REGULATIONS:
OSHA: NA
CERCLA RQ*: 182 gal.
RCRA**: NA
SARA Title III
SARA 311 CATEGORIES:
1.Immediate (Acute) Health Effects; YES
2. Delayed (Chronic) Health Effect; YES
3. Fire Hazard; YES
4. Sudden Release of Pressure Hazard; NO
5. Reactivity Hazard; NO
STATE REGULATIONS: Each state may promulgate standards more stringent than the Federal government. This section cannot encompass an inclusive list of all state regulations. Therefore, the user should consult state or local authorities.
*RQ: Reportable Quantity
**RCRA waste codes must be determined on a case by case basis (i.e., spill, processing waste, etc.). The waste code presented is based on available product characteristics only.

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SECTION 16: OTHER INFORMATION
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REASON FOR ISSUE: Multiple changes throughout MSDS.
APPROVAL DATE: 1/18/95
REVISION DATE: 1/18/95
SUPERSEDES DATE: 3/31/94
MSDS NUMBER: 0034
EMERGENCY TELEPHONE #: (800) 892-0099
Revision Number: 1
NDA - No Data Available
NA - Not Applicable
THE INFORMATION IN THIS MSDS IS BASED ON DATA AVAILABLE TO US AS OF THE REVISION DATE GIVEN HEREIN, AND BELIEVED TO BE CORRECT. CONTACT VALENT USA CORPORATION TO CONFIRM IF YOU HAVE THE MOST CURRENT MSDS. JUDGEMENTS AS TO THE SUITABILITY OF INFORMATION HEREIN FOR THE INDIVIDUAL'S OWN USE OR PURPOSES ARE NECESSARILY THE INDIVIDUAL'S OWN RESPONSIBILITY. ALTHOUGH REASONABLE CARE HAS BEEN TAKEN IN THE PREPARATION OF SUCH INFORMATION, VALENT EXTENDS NO WARRANTIES, MAKES NO REPRESENTATIONS, AND ASSUMES NO RESPONSIBILITY AS TO THE ACCURACY OR SUITABILITY OF SUCH INFORMATION FOR APPLICATION TO THE INDIVIDUAL'S PURPOSES OR THE CONSEQUENCES OF ITS USE.