Return to Submission of Objections to EPA's Final Rule on Sulfuryl fluoride

APPENDIX 1-K.
WHEAT. US EPA Pesticide Residue Tolerances as of March 2004

March 23, 2004, Submission to US EPA
from Fluoride Action Network:
Objections and Request for a Hearing
RE: US EPA's January 23, 2004, Final Rule for Sulfuryl Fluoride.

 

Sulfuryl fluoride residue tolerances Inorganic fluoride PPM Sulfuryl fluoride PPM
Wheat, bran, postharvest 40.0 0.05
Wheat, flour, postharvest 125.0 0.05
Wheat, germ, postharvest 130.0 0.02
Wheat, grain, postharvest 40.04 0.1
Wheat, milled byproducts, postharvest 130.0 0.05
Wheat, shorts, postharvest 40.0 0.05

 

Table 1. Summary of WHEAT:
US EPA Pesticide Residue Tolerances as of March 1, 2004*

Category

 Number of pesticides with approved residue tolerances ** Number of pesticide products that use NaF as an "inert" Number of applications for each pesticide product with NaF as an "inert" Estimated fluoride residue levels

WHEAT,
GRAIN

TABLE 2

78
unknown
unknown
unknown
WHEAT,
BRAN

TABLE 3
8
unknown
unknown
unknown
WHEAT,
GERM

TABLE 4
1
unknown
unknown
unknown
WHEAT,
FLOUR

TABLE 3
2
unknown
unknown
unknown
WHEAT, SHORTS

TABLE 3
2
unknown
unknown
unknown
WHEAT,
MILLED
BYPRODUCTS

TABLE 3
5
unknown
unknown
unknown
Total

96

Note:

* Not listed in this Table or the Tables below: pesticides with more than one tolerance in this category. For example, metabolites in some pesticides also receive residue tolerances.

** tolerances for Methyl bromide and/or its inorganic compounds are not included


Information for the following comes from an Online search on March 4, 2004 from
EPA's website: http://www.epa.gov/pesticides/food/viewtols.htm

Table 2. Wheat, grain - Residue Tolerances as of March 2004

Fluorinated pesticides highlighted in green
Number Pesticide Crop Residue tolerance
PPM		 CFR FAN Notes:
1 Clodinafop WHEAT,
GRAIN  
0.1
 180.559 Z13.
2 Clodinafop WHEAT,
GRAIN  
0.1
 180.559

Z13.

likely metabolite
3 Cyfluthrin WHEAT,
GRAIN  
2
 180.436  
4 Diflubenzuron WHEAT,
GRAIN   
0.05 
 180.377   
5 Flucarbazone-sodium WHEAT,
GRAIN
0.01
 180.562 Z11. 
6 Flufenacet WHEAT,
GRAIN
1
 180.527  
7 Fluroxypyr 1-methylheptyl ester WHEAT,
GRAIN
0.5
 180.535 T.
8 Lambda-Cyhalothrin WHEAT,
GRAIN
0.05
 180.438  
9 Trifloxystrobin WHEAT,
GRAIN
0.05
 180.555 Q. 
10 Trifluralin WHEAT,
GRAIN  
0.05
 180.207  
11 TCMTB WHEAT,
GRAIN
0.1
 180.288 U.
12 2-4,D WHEAT,
GRAIN
0.5
 180.142B  
13 Tralkoxydim WHEAT,
GRAIN
0.02
 180.548 V. 
14 Spinosad WHEAT,
GRAIN
0.02
 180.495 C. 
15 Clopyralid, monoethanolamine salt WHEAT,
GRAIN 
 3
 180.431  W.
16 Paraquat dichloride WHEAT,
GRAIN 
0.05
 180.205 A. 
17 Thiamethoxam WHEAT,
GRAIN 
0.02
 180.565 P.  
18 Triticonazole WHEAT,
GRAIN 
0.05
 180.583 X. 
19 Acetochlor WHEAT,
GRAIN
0.02
 180.470  
20 Allethrin WHEAT,
GRAIN
2
 180.113  
21 Atrazine WHEAT,
GRAIN 
0.25 
 180.220   
22 Azoxystrobin WHEAT,
GRAIN 
0.1
 180.507  
23 Benomyl WHEAT,
GRAIN 
0.2
 180.294  
24 Bromoxynil WHEAT,
GRAIN 
0.1
 180.324  
25 Bromoxynil WHEAT,
GRAIN 
0.1
 180.324C  
26 Pyraclostrobin WHEAT,
GRAIN 
0.02
 180.582 H. 
27 Carbaryl WHEAT,
GRAIN 
3
 180.169  
28 Carbofuran WHEAT,
GRAIN  
0.2 
 180.254    
29 Carboxin WHEAT,
GRAIN  
0.2 
 180.301  
30 Chlorpyrifos WHEAT,
GRAIN  
0.5
 180.342  
31 Chlorpyrifos-methyl WHEAT,
GRAIN  
6
 180.419  
32 Chlorsulfuron WHEAT,
GRAIN  
0.1
 180.405  
33 Clofencet WHEAT,
GRAIN  
250
 180.497  
34 Cyanazine WHEAT,
GRAIN   
0.1
 180.307  
35 Dicamba WHEAT,
GRAIN  
2
 180.227  
36 Diclofop-methyl WHEAT,
GRAIN  
0.1
 180.385  
37 Difenoconazole WHEAT,
GRAIN  
0.1
 180.475  
38 Difenzoquat WHEAT,
GRAIN  
0.05
 180.369  
39 Dimethoate WHEAT,
GRAIN  
0.04
 180.204  
40 Disulfoton WHEAT,
GRAIN  
0.3
 180.183  
41 Diuron WHEAT,
GRAIN  
1
 180.106  
42 Endosulfan WHEAT,
GRAIN  
0.1
 180.182  
43 Ethephon WHEAT,
GRAIN  
2
 180.300  
44 Etridiazole WHEAT,
GRAIN  
0.05
 180.370  
45 Fenoxaprop WHEAT,
GRAIN   
0.05 
  180.430  
46 Fenridazon WHEAT,
GRAIN  
40
 180.423  
47 Glyphosate WHEAT,
GRAIN  
5
 180.364  
48 Imazalil WHEAT,
GRAIN  
0.05 
 180.413  
49 Imazamethabenz WHEAT,
GRAIN  
0.1
 180.437  
50 Imidacloprid WHEAT,
GRAIN  
0.05 
 180.472  
51 Sulfosulfuron WHEAT,
GRAIN  
0.02
 180.552 Z12. 
52 Linuron WHEAT,
GRAIN   
0.25 
 180.184  
53 MCPA (and salts and esters) WHEAT,
GRAIN  
0.1
 180.339  
54 Malathion WHEAT,
GRAIN  
8
 180.111  
55 Mancozeb WHEAT,
GRAIN  
5
 180.176  
56 Metalaxyl WHEAT,
GRAIN  
0.2
 180.408  
57 Methomyl WHEAT,
GRAIN  
1
 180.253  
58 Metolachlor WHEAT,
GRAIN  
0.1
 180.368  
59 Metribuzin WHEAT,
GRAIN   
0.75 
 180.332   
60 Metsulfuron WHEAT,
GRAIN  
0.1
 180.428  
61 Nitrapyrin WHEAT,
GRAIN  
0.1
 180.350  
62 Phorate WHEAT,
GRAIN  
0.05
 180.206  
63 Phosphine WHEAT,
GRAIN   
0.1 
 180.225   
64 Picloram WHEAT,
GRAIN  
0.5
 180.292  
65 Propanil WHEAT,
GRAIN  
0.2
 180.274  
66 Propiconazole WHEAT,
GRAIN  
0.1 
 180.434  
67 Sulfosate WHEAT,
GRAIN   
10
 180.489    
68 Tebuconazole WHEAT,
GRAIN  
0.05
 180.474  
69 Tepraloxydim WHEAT,
GRAIN  
0.02
 180.548 Z19. 
70 Thiabendazole WHEAT,
GRAIN  
1
 180.242  
71 Thifensulfuron WHEAT,
GRAIN  
0.05
 180.439  
72 Thiophanate-methyl WHEAT,
GRAIN   
0.05 
 180.371    
73 Triadimefon WHEAT,
GRAIN  
1
 180.410  
74 Triadimenol WHEAT,
GRAIN  
0.05
 180.450  
75 Triallate WHEAT,
GRAIN  
0.05
 180.314  
76 Triasulfuron WHEAT,
GRAIN   
0.02 
 180.459    
77 Tribenuron WHEAT,
GRAIN  
0.05
 180.451  
78 Zinc phosphide (Zn3P2) WHEAT,
GRAIN  
0.05
 180.284  

 

Table 3. WHEAT, BRAN  - Residue Tolerances as of March 2004

Fluorinated pesticides highlighted in green 
Number Pesticide Crop Residue tolerance
PPM		 CFR FAN Notes:
1 Lambda-Cyhalothrin WHEAT,
BRAN
0.2
 180.438  
2 Trifloxystrobin WHEAT,
BRAN
0.15
 180.555 Q. 
3 Spinosad WHEAT,
BRAN
0.15
 180.495 C.  
4 Spinosad WHEAT,
BRAN
0.15
 180.495 likely metabolite  
5 Azoxystrobin WHEAT,
BRAN
0.2
 180.507  
6 Ethephon WHEAT,
BRAN
5
 180.300  
7 Metribuzin WHEAT,
BRAN
3
 180.332  
8 Sulfosate WHEAT,
BRAN
30
 180.489  

 

Table 4. WHEAT, GERM - Residue Tolerances as of March 2004
Number Pesticide Crop Residue tolerance
PPM		 CFR FAN Notes:
1 Metribuzin WHEAT,
GERM
3
 180.332  

 

Table 5. WHEAT, FLOUR - Residue Tolerances as of March 2004
Number Pesticide Crop Residue tolerance
PPM		 CFR FAN Notes:
1 Spinosad WHEAT,
FLOUR
0.15
 180.495 C. 
2 Pirimiphos-methyl WHEAT,
FLOUR
8
 180.409  

 

Table 5. WHEAT, SHORTS - Residue Tolerances as of March 2004
Number Pesticide Crop Residue tolerance
PPM		 CFR FAN Notes:
1 Metribuzin WHEAT, SHORTS
3
 180.332  
2 Sulfosate WHEAT, SHORTS
20
 180.489

 

 

Table 5. WHEAT, MILLED BYPRODUCTS - Residue Tolerances as of March 2004

Fluorinated pesticides highlighted in green
Number Pesticide Crop Residue tolerance
PPM		 CFR FAN Notes:
1 Diflubenzuron WHEAT,
MILLED
BYPRODUCTS
0.1
 180.377  
2 2-4,D WHEAT,
MILLED
BYPRODUCTS
2
 180.142  
3 Spinosad WHEAT,
MILLED
BYPRODUCTS
0.15
 180.495 C. 
4 Mancozeb WHEAT,
MILLED
BYPRODUCTS
20
 180.176  
5 Sulfosate WHEAT,
MILLED
BYPRODUCTS
1.5
 180.489  

 

Notes.
A. EPA lists Paraquat dichloride:
4,4'-Bipyridinium, 1,1'-dimethyl-, dichloride  
B. EPA lists Pyriproxyfen:
Pyridine, 2-(1-methyl-2-(4-phenoxyphenoxy)ethoxy)-

C. EPA lists Spinosad:
2-{(6-Deoxy-2,3,4-tri-O-methyl-alpha-L-mannopyranosyl)oxy}-13-
{{5-(dimethylamino)tetrahydro-6-methyl-2H-pyran-2-yl}oxy}-9-ethyl-2,3,3a,5a,5b,6,9,10,11,12,13,14,16a,16b-tetradecahydro-14-methyl-1H-as-Indaceno{3,2-d}oxacyclododecin-7,15-dione,(Cont'd
Qual

D. EPA lists Pyridaben:
3(2H)-Pyridazinone, 4-chloro-2-(1,1-dimethylethyl)-5-(((4-(1,1-dimethylethyl)phenyl)methyl)thio)-  

E. EPA lists Nicobifen:
3-Pyridinecarboxamide, 2-chloro-N-(4'-chloro?1,1'-biphenylU-2-yl)-
F. EPA lists Diquat dibromide:
6,7-Dihydrodipyrido(1,2-a:2',1'-c)pyrazinediium dibromide
G. EPA lists Methoxyfenozide:
Benzoic acid, 3-methoxy-2-methyl-.2-(3,5-dimethylbenzoyl)-2-(1,1-dimethylethyl)hydrazide
H. EPA lists Pyraclostrobin:
Carbamic acid, [2-[[[1-(4-chlorophenyl)-1H-pyrazol-3-yl]oxy]methyl]phenyl]methoxy-, methyl ester
I. EPA lists Bifenazate:
Hydrazinecarboxylic acid, 2-(4-methoxy{1,1'-biphenyl}-3-yl)-, 1-methylethyl ester
J. EPA lists Cyprodinil:
2-Pyrimidinamine, 4-cyclopropyl-6-methyl-N-phenyl-
K. EPA lists
L. EPA lists Pyridaben:
3(2H)-Pyridazinone, 4-chloro-2-(1,1-dimethylethyl)-5-(((4-(1,1-dimethylethyl)phenyl)methyl)thio)-

M. EPA lists Buprofezin:
4H-1,3,5-Thiadiazin-4-one, 2-{(1,1-dimethylethyl)imino}tetrahydro-3-(1-methylethyl)-5-phenyl-

N. EPA lists Fenhexamid:
Cyclohexanecarboxamide, N-(2,3-dichloro-4-hydroxyphenyl)-1-methyl-
O. EPA lists Pymetrozine:
1,2,4-Triazin-3(2H)-one, 4,5-dihydro-6-methyl-4-{(3-pyridinylmethylene)amino}-, (E)-
P. EPA lists Thiamethoxam:
4H-1,3,5-Oxadiazin-4-imine, 3-[(2-chloro-5-thiazolyl)methyl]tetrahydro-5-methyl-N-nitro-
Q. EPA lists Trifloxystrobin:
Benzeneacetic acid,.alpha.-(methoxyimino)-2-{{{{1-{3-(trifluoromethyl)phenyl}ethylidene}amino}oxy}methyl}-, methyl ester, (E,E)-
R. EPA lists Trifloxysulfuron-sodium:
2-Pyridinesulfonamide, N-[[(4,6-dimethoxy-2-pyrimidinyl)amino]carbonyl]-3-(2,2,2-trifluoroethoxy)-, monosodium salt, monohydrate
S. Aluminum phosphide and Phosphine have the same CFR number. 
T. EPA Lists Fluroxypyr 1-methylheptyl ester:
Acetic acid, ((4-amino-3,5-dichloro-6-fluoro-2-pyridinyl)oxy)-, 1-methylheptyl ester
U. EPA lists TCMTB:
2-(Thiocyanomethylthio)benzothiazole
V. EPA lists Tralkoxydim:
2-Cyclohexen-1-one, 2-{1-(ethoxyimino)propyl}-3-hydroxy-5-(2,4,6-trimethylphenyl)-
W. EPA lists Clopyralid, monoethanolamine salt:
3,6-Dichloro-2-pyridinecarboxylic acid, alkanolamine salts (of ethanol and isopropanol series) 
X. EPA lists Triticonazole:
5-[(4-Chlorophenyl)methylene]-2,2-dimethyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentanol 
Y.  EPA lists Flufenacet:
Acetamide, N-(4-fluorophenyl)-N-(1-methylethyl)-2-((5-(trifluoromethyl)-1,3,4-thiadiazol-2-yl)oxy)-
Z. EPA lists Flufenpyr-ethyl:
Acetic acid, [2-chloro-4-fluoro-5-[5-methyl-6-oxo-4-(trifluoromethyl)-1(6H)-pyridazinyl]phenoxy]-, ethyl ester  
Z1. EPA lists Fluthiacet-methyl:
Acetic acid, ((2-chloro-4-fluoro-5-((tetrahydro-3-oxo-1H,3H-(1,3,4)thiadiazolo(3,4-a)pyridazin-1-ylidene)amino)phenyl)thio)-, methyl ester

Z2. EPA lists Pyraflufen-ethyl:
Ethyl 2-chloro-5-[4-chloro-(5-difluoromethoxy)-1-methyl-1H-pyrazol-3-yl]-4-fluorophenoxyacetate

Z3. EPA lists Isoxaflutole:
Methanone,(5-cyclopropyl-4-isoxazolyl){2-(methylsulfonyl)-4-(trifluoromethyl)phenyl}-
Z4. EPA lists Diflufenzopyr:
2-{1-{{{(3,5-difluorophenyl)amino}carbonyl}hydrazono}ethyl}-3-pyridinecarboxylic acid
Z5. EPA lists Mesotrione:
2-{4-(methylsulfonyl)-2-nitrobenzoyl}- 1,3-cyclohexanedione
Z6. EPA lists Iodosulfuron methyl, sodium salt:
4-Iodo-2-????(4-methoxy-6-methyl-1,3,5-triazin-2-yl-)aminoUcarbonylUaminoUsulfonylUbenzoic acid methyl ester, monosodium salt
Z7. EPA lists Bentazon, sodium salt:
3-Isopropyl-1H-2,1,3-benzothiadiazin-4(3H)-one-2,2-dioxide, sodium salt  
Z8. EPA lists Bispyribac-sodium:
Benzoic acid, 2,6-bis[(4,6-dimethoxy-2-pyrimidinyl)oxy]-, sodium salt
Z9. EPA lists Acifluorfen, sodium salt:
Benzoic acid, 5-(2-chloro-4-(trifluoromethyl)phenoxy)-2-nitro-, sodium salt
Z10. EPA lists Cyhalofop-butyl:
Propanoic acid, 2-?4-(4-cyano-2-fluorophenoxy)phenoxyU-, butyl ester, (R)-
Z11. EPA lists Flucarbazone-sodium:
1H-1,2,4-Triazole-1-carboxamide,4,5-dihydro-3-methoxy-4-methyl-5-oxo-N-[[2-(trifluoromethoxy)phenyl]sulfonyl]-,sodium salt

Z12. EPA lists Sulfosulfuron:
Imidazol{1,2-a}pyridine-3-sulfonamide, N-{{(4,6-dimethoxy-2-pyrimidinyl)amino}carbonyl}-2-(ethylsulfonyl)-

Z13. EPA lists Clodinafop:
Propanoic acid, 2-{4{(5-chloro-3-fluoro-2-pyridinyl)oxy}phenoxy}-, 2-propynyl ester
Z19. EPA lists Tepraloxydim:
2-Cyclohexen-1-one, 2-{1-{{(3-chloro-2-propenyl)oxy}imino}propyl}-3-hydroxy-5-(tetrahydro-2H-pyran-4-yl)-,(E,?)-