Fluorinated pesticides that emit hydrogen fluoride when burned  
 
http://www.ilo.org/public/english/protection/safework/cis/products/icsc/dtasht/index.htm

combustion products fluoride - hsdb

HAZARDOUS COMBUSTION PRODUCTS FROM MUNICIPAL WASTE INCINERATION
Authors:
MARTY MA
Source: OCCUPATIONAL MEDICINE (PHILADELPHIA); 8 (3). 1993. 603-620.
1207-31-9
51207-31-9
16984-48-8 - fluoride ion

Name of Pesticide Chemical Formula / Activity Statement Reference

SODIUM ACIFLUORFEN

(Bonide KleenUp Grass and Weed Killer)

  HAZARDOUS DECOMPOSITION PRODUCTS: Heating this material (Acifloufen Component) may generate hydrogen chloride, hydrogen flouride and nitrogen oxide

Bonide Products, Inc.

MSDS

ID # 71995144

March 7, 2000

Beta-cyfluthrin   Hazards from combustion products:
In a fire, formation of hydrogen chloride, hydrogen cyanide, hydrogen fluoride, carbon monoxide, carbon dioxide, aldehydes, ketones and nitrogen oxides can be expected.

BAyer CropScience MSDS

November 27, 2003

Bifenthrin

(TALSTAR® LAWN & TREE FLOWABLE INSECTICIDE/MITICIDE)

  Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, chlorine, fluorine, hydrogen chloride and hydrogen fluoride

MSDS

Ref. No. 82657-04-3-37
August 13, 1998

Carfentrazone-ethyl

(AIM EC Herbicide)

  Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, nitrogen oxides, hydrogen chloride, and hydrogen fluoride.

FMC Corporation
MSDS
Ref. No. 128639-02-1-13
September 1, 2004

Cyfluthrin   Fire Fighting Measures.
Hazards from combustion products:
In the event of a fire the formation of hydrogen chloride, hydrogen fluoride and oxides of nitrogen must be anticipated

Bayer CropScience

MSDS

October 20, 2002

Fipronil  

Hazardous Products of Decomposition: Hydrogen fluoride, Oxides of nitrogen, sulfur, carbon oxides, hydrochloric acid

"Controlled incineration of the formuation: as for active substances. Incineration at 800ºC and 1200ºC, under excess oxygen, with three minutes' retention time for the solids and approximately two seconds' retention time for the gas, results in a Destruction Removal Efficiency (DRE) of ≥99.99% for the active ingredient. A large number of decomposition products were identified especialy at 800ºC. A lesser number of decomposition products were identified at 1200ºC. Hydrogen fluoride was detected in the exhaust gas with a concentration of approximately 330 mg/m3. 1.63% of the product stayed in the furnace after three minutes of incineration at 800ºC, but only 0.54% stated at approximately 200ºC. In both cass, less than 0.3% of the active ingredient was measured in the residue". (page 14).
Ref: April 204. Evaluation on : Fipronil (Horticultural Uses). No. 212. UK Dept. for Environment, Food and Rural Affairs, Pesticides Safety Directory.

Bayer Environmental Science
MSDS

Revised April 22, 2004

Flumethrin

(Bayticol Cattle Dip and Spray)

7.5% Flumethrin

>60% solvent naptha (petroleum), heavy aromatic

Hazardous Combustion Products:
Thermal decomposition products include hydrogen chloride, hydrogen cyanide, hydrogen fluoride, carbon monoxide, and nitrogen oxides.

A18014/05/AUS

MSDS

Fluoroacetamide

C2H4 F NO

Rodenticide, Insecticide (unclassified)

CAS No. 640-19-7
 

Fluoroacetamide releases toxic and irritating fumes of fluoride and oxides of nitrogen when heated to decomposition. Hazardous Substances data bank

Fluorosilicic Acid

also known as

Hexafluorosilicic acid
Dihydrogen hexafluorosilicate
Fluosilicic acid
Hydrosilicofluoric acid

16961-83-4 Chemical dangers:
The substance decomposes on heating producing toxic fumes including hydrogen fluoride ... This substance (anhydrous form) dissociates almost instantly into silicon tetrafluoride and corrosive and toxic hydrogen fluoride.

1233
October 2004

International Labor Organization

International Occupational Safety and Health Information Centre

Flutolanil

FAN online

C17H16 F3 NO2 

Fungicide (benzanilide)

Chemical Dangers:
The substance decomposes on burning producing toxic and corrosive fumes including hydrogen fluoride, nitrogen oxides, carbon monoxide

Fire:
Combustible. Liquid formulations containing organic solvents may be flammable.

1265
April 2004

International Programme on Chemical Safety and the European Commission.

Hexaflumuron   Chemical Dangers:
The substance decomposes on burning producing toxic and corrosive fumes incluging nitrogen oxides, hydrogen chloride, hydrogen fluoride.

1266
October 1995

International Programme on Chemical Safety and the European Commission.

Hydramethylnon   Combustion Products:
Thermal decomposition may produce hydrogen fluoride and oxides of carbon and nitrogen

Wellmark International
MSDS

January 2004

Methanesulfonyl fluoride
CAS No. 558-25-8
 

Fumigant, Insecticide, Wood Preservative

Organophosphate pesticide - no longer being used

Hazardous Decomposition Products: Carbon monoxide, oxides of sulfur, carbon dioxide, hydrogen fluoride gas, fluoride fumes. MSDS ACC # 20835

Oxyfluorfen

(Goal 2XL Herbicide)

  Fire Fighting Measure.
Unusual Hazards: Pesticide particulates can become airborne. Combustion generates toxic fumes of the following: hydrogen chloride - hydrogen fluoride - nitrogen oxides.
1998 MSDS by C&P Press

Siloxanes and silicones,
Me 3,3,3-trifluoropropyl

CAS No. 63148-56-1 

  emits HF & perfluorocarbons

MSDS

Vac Goop® Antiseize thread lubricant

Sodium Fluoracetate
CAS No. 62-74-8

Compound 1080 is a trade name.

C2H2FO2.Na / CH2FCOONa

Rodenticide, Insecticide (unclassified)

The substance decomposes on heating or on burning producing toxic fumes including hydrogen fluoride.

IPCS
ICSC: 0484

International
Programme on
Chemical Safety

Sulfentrazone

(Spartan 4F Herbicide)

  Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, nitrogen oxides, sulfur oxides, hydrogen chloride, hydrogen fluoride
FMC Corporation MSDS
Ref. No.: 122836-35-5-2
Revision No. 12
September 27, 2004

Sulfluramid

(FLUORGUARD ANT BAIT STATION INSECTICIDE)

  Hazardous Decomposition Products:
May produce hydrogen fluoride

MSDS
Ref. No. 4151-50-2-2
Revision No: 3

August 13, 1998

tau-Fluvalinate

(Mavrik Perimeter)

  Combustion Products:
Hydrogen cyanide, hydrogen chloride and hydrogen fluoride may result from combustion.

Wellmark International MSDS

November 2002

Trifloxystrobin   Unusual Fire and Explosion Hazards:
In fire situations, toxic and corrosive hydrogen cyanide, hydrogen fluoride, carbon monoxide, nitrogen oxide and oxides of sulfur may be released.

Gustafson LLC
MSDS

September 2003

Triflumuron   In a fire, formation of hydrogen chloride, hydrogen cyanide, hydrogen fluoride, carbon monoxide and nitrogen oxides can be expected.

Bayer CropScience

MSDS for Alsystin 250 Larvicide

August 9, 2004

Trifluralin   Thermal decomposition of trifluralin will release corrosive fumes of hydrogen fluoride and toxic oxides of nitrogen (7).

September 1993

Extoxnet

       

       
Acrinathrin   No infor available  
       
       

INORGANIC
       
       
       

Sodium fluosilicate

16893-85-9

F6 Na2Si

Insecticide, Wood preservative, US EPA List 3 Inert

Hazardous Decomposition or Byproducts: HF gas, F compounds, NaO2 from contact with some metals. July 11, 2001 - MSDS. GM16893-85-9 Foam Gelling Agent. GM Foam, Inc.
       
       
       

 

Curiosity"

 

http://www.bayercropscienceus.com/=file:Labels%20MSDS/20050112170622696761868115169381/file
No fluorinated pesticide:
Bayer Crop Science

Hazardous Products of Decomposition:
In case of fire hazardous decomposition products may be produced such as:
CO2
Carbon Monoxide
NOX
Sulphyr oxides
Hydrogen fluoride
Hydrogen cyanide (hydrocyanic acid)
HCL

http://www.gustafson.com/MSDS/MagnaBritenerGSS.pdf


For Michael: http://www.gbotubes.com/msds/glucose.pdf

 

 
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